用Mossbauer谱研究了快速凝固Al-Fe-V-Si合金的微结构,结果表明,合金中Fe原子存在α-Al(Fe),α-Al(Fe-Fe)替代固溶体及α-Al13(Fe,V)3Si金属间化合物三种组态,高温热曝露状态除4.3%Fe合金(原子分数)α-Al(Fe-Fe)组态消失外,其它合金组态类型不变,但含量发生相对变化,急冷态和退火态α-Al晶格常数随合金中Fe含量增加呈现不同程度的下降趋势,归因于两种状态组分原子Fe,V和Si含量的变化。
By means of Mossbauer spectroscopy analyses, it is indicated that there are three kinds of configurations for Fe atoms corresponding to α-Al(Fe) and α-Al(Fe-Fe) solid solutions and α-Al13(Fe,V)3Si intermetallic compound in liquid-quenched Al-Fe-V-Si alloys. Except for the absence of α-Al(Fe-Fe) configuration in Al93.3Fe4.3V0.7Si1.7 alloy, the other Fe atomic configurations do not change during the annealing at 755 K for 500 h. However,the relative contents of these configurations have changed. The lattice parameters of α-Al matrix decreased with increasing Fe content (4.3, 5.4, 6.4 (atomic fracti0n, %)) for three RS Al-Fe-V-Si alloys in as-cast and heat-treated states. In addition, the possible configurations of V and Si atoms have been discussed by using the results of Mossbauer spectra and matrix lattice parameters.
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