杯芳烃作为继冠醚和环糊精之后的第三代主体分子具有独特的分子离子识别能力和结构易修饰性.利用聚合物稳定性好、易于加工的特性将杯芳烃键合到聚合物上,有望制备出新型功能高分子材料.共聚法是一种制备含杯芳烃聚合物的重要方法,通过在杯芳烃上沿或下沿接上可聚合基团制备含杯芳烃单体,然后均聚或与其它单体共聚形成聚合物.主要阐述了含杯芳烃单体及其聚合方法的研究进展.
As the third generation of host molecules after crown ethers and cyclodextrins in supramolecular chemistry, calixarenes are of peculiar moleculars or ions recognition ability and structure which can be readily modified. Considering the good stability and machinability of polymer materials, novel functional polymers are expected to be developed by bonding calixarenes into the polymers. In many cases, calixarene-containing monomers are produced by bonding polymeric groups into the upper or lower rim of calixarenes, followed by homopolymerization or copolymerization in order to obtain calixarene-containing polymers. The recent progress in calixarene-containing monomers and their polymerization methodology is reviewed.
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