分别以碳毡和二维碳纤维为预制体,采用化学液相气化渗入法结合熔融渗硅反应法快速制备了C/C-SiC陶瓷复合材料.对这种材料的密度和气孔率进行了表征,并通过XRD,OM和SEM等方法对其相组成、显微结构和反应机理进行了研究.结果表明:不同预制体制备的C/C-SiC材料密度和气孔率分别为~2.0 g/cm3和~1.0%.其相组成包括反应生成β-SiC以及未反应的游离Si和C.C/C-SiC中纤维被环状的沉积碳包裹,生成SiC的反应只发生在Si与沉积碳之间,纤维没有损伤.Si,C和SiC各相分布和含量因预制体的不同而有明显差异.
参考文献
[1] | Fitzer E;Manocha L M.Carbon Reinforcements and Carbon/Carbon Composites[M].New York:Springer-Verlag,1998:295. |
[2] | Prewo K M .[J].American Ceramic Society Bulletin,1989,68(02):395. |
[3] | Krenkel W .[J].Ceramic Engineering and Science Proceedings,2003,24(04):583. |
[4] | Heidenreich B;Krenkel W;Lexow B .[J].Ceramic Engineering and Science Proceedings,2003,24(03):375. |
[5] | Golecki I .[J].Materials Science and Engineering R:Reports,1997,20:37. |
[6] | Houdayer M;Spitz J;Tran Van D .[P].US 4472454,1984. |
[7] | Bruneton E.;Oberlin A.;Narcy B. .CARBON-CARBON COMPOSITES PREPARED BY A RAPID DENSIFICATION PROCESS I - SYNTHESIS AND PHYSICO-CHEMICAL DATA[J].Carbon: An International Journal Sponsored by the American Carbon Society,1997(10/11):1593-1598. |
[8] | 嵇阿琳,霍肖旭,马伯信.CLVD 法制备C/C复合材料工艺探索研究[J].固体火箭技术,2001(03):68-70. |
[9] | Hillig W .[J].American Ceramic Society Bulletin,1994,73(04):56. |
[10] | David P;Stinton A;Caputo R .[J].American Ceramic Society Bulletin,1986,65(02):347. |
[11] | Nakano K;Kamiya A;Ogawa H et al.[J].Journal of the Ceramic Society of Japan,1992,100(1160):472. |
[12] | 姜华;金志浩;王永兰 .[J].稀有金属材料与工程,2005,34(z2):101. |
[13] | Li JG.;Hausner H. .REACTIVE WETTING IN THE LIQUID-SILICON/SOLID-CARBON SYSTEM[J].Journal of the American Ceramic Society,1996(4):873-880. |
[14] | Messner R;Chiang Y M .[J].Journal of the American Ceramic Society,1990,73(05):1193. |
[15] | Zhou H;Singh R .[J].Journal of the American Ceramic Society,1995,78(09):2456. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%