欢迎登录材料期刊网

材料期刊网

高级检索

以聚苯乙烯单层胶体晶体为模板,分别采用溶液浸渍法和磁控溅射法制备TiO2和ZnO二维纳米阵列。研究了前驱体浓度、溅射时间和溅射功率对纳米阵列形态的影响,研究发现随着前驱体浓度的降低, TiO2纳米阵列的形貌由孔状变为环状。对于特定的ZnO孔状阵列,随着溅射功率的增大和溅射时间的延长,阵列的表面形貌也出现了明显的变化。结果表明,利用模板法制备的纳米阵列的形态可通过实验参数来进行调控。

Titanium dioxide( TiO2 ) and zinc oxide( ZnO) two dimensional nanoarrays were fabricated by solution dip and magnetron sputtering via monolayer polystyrene colloidal crystal template,respectively. The effects of pre-cursor concentration,sputtering time and sputtering power on the morphology of nanoarrays were studied. The mor-phology of TiO2 nanoarray changes from pore into ring with the decreasing precursor concentration. The surface of ZnO pore array was also clearly changed with the increased power and the prolonged time. The results indicated that the morphology of nanoarrays could be controlled by the experiment parameters.

参考文献

[1] JOEL HENZIE;JEREMY E.BARTON;CHRISTOPHER L.STENDER;TERI W.ODOM .Large-Area Nanoscale Patterning:Chemistry Meets Fabrication[J].Accounts of Chemical Research,2006(4):249-257.
[2] Yong Lei;Shikuan Yang;Minghong Wu .Surface patterning using templates: concept, properties and device applications[J].Chemical Society Reviews,2011(3):1247-1258.
[3] Xiaozhou Ye;Limin Qi .Two-dimensionally patterned nanostructures based on monolayer colloidal crystals: Controllable fabrication, assembly, and applications[J].Nano Today,2011(6):608-631.
[4] Li Y;Cai W;Duan G .Ordered micro/nanostructured arrays based on the monolayer colloidal crystals[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(3):615-624.
[5] Ye X Z;Qi L M .Recent advances in fabrication of monolayer colloidal crystals and their inverse replicas[J].Sci China Chem,2014,57:58-69.
[6] Zhigang Li;Peisheng Liu;Yanping Liu .Fabrication of size-controllable Fe2O3 nanoring array via colloidal lithography[J].Nanoscale,2011(7):2743-2747.
[7] Zhigang Li;Wenwu Zhong;Xiaoming Li .Strong room-temperature ferromagnetism of pure ZnO nanostructure arrays via colloidal template[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,2013(41):6807-6812.
[8] Li Y;Sasaki T;Shimizu Y;Koshizaki N .Hexagonal-Close-Packed, Hierarchical Amorphous TiO2 Nanocolumn Arrays: Transferability, Enhanced Photocatalytic Activity, and Superamphiphilicity without UV Irradiation[J].Journal of the American Chemical Society,2008(44):14755-14762.
[9] Zhang G;Wang DY .Fabrication of heterogeneous binary arrays of nanoparticles via colloidal lithography[J].Journal of the American Chemical Society,2008(17):5616-5617.
[10] Duan, G.;Lv, F.;Cai, W.;Luo, Y.;Li, Y.;Liu, G. .General synthesis of 2D ordered hollow sphere arrays based on nonshadow deposition dominated colloidal lithography[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(9):6295-6302.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%