以细菌纤维素(BC)为载体,用溶胶一凝胶法原位生成稀土镧和铈元素(La,Ce)掺杂的二氧化钛复合膜,以甲基橙为目标降解物,考察了复合膜的光催化活性.结果表明:稀土元素已引入TiO2/BC复合膜中;掺杂TiO2的晶型为锐钛矿型;掺杂稀土的TiO2/BC复合膜的光催化活性比未掺杂的有较大提高;钵掺杂的TiO2/BC复合膜的光催化性能优于铡掺杂的;Ce(4+)掺杂的最适浓度为2 mmol/L,而La(3+)掺杂的最适浓度为5 mmol/L;稀土掺杂的TiO2/BC复合膜对甲基橙溶液重复降解5次的降解率仍高于70%.
参考文献
[1] | S.Yamanaaka,K.Watanabe,N.Kitamura,M.Iguchi,S.Mitsvhashi,Y.Nishi,M.Uryu,Production of Bacterial Cellulose by Acetobacter xylinum from watermelon peel juice,J.Mater.Sci.,24,3141(1989) |
[2] | Y.Z.Wan,L.Hong,S.R.Jia,Y.Huang,Y.Zhu,Y.L.Wang,H.J.Jiang,Synthesis and characterization of hydroxyapatite-bacterial cellulose nanocomposites,Composites Science and Technology,66(11-12),1825(2006) |
[3] | H.S.Barud,R.M.N.Assunao,M.A.U.Martines,J.DexpertGhys,R.F.C.Marques,Y.Messaddeq,S.J.L.Ribeiro,Bacterial cellulose-silica organic-inorganic hybrids,Journal of Sol-Gel Science Technology,46(3),363(2008) |
[4] | C.Zollfrank,H.Scheel,P.Greil,Regioselectively ordered silica nanobubes by molecular templating,Advanced Materials,19(7),984(2007) |
[5] | S.H.Yoon,H.J.Jin,M.C.Kook,Y.R.Pyun,Electrically conductive bacterial cellulose by incorporation of carbon nanotubes,Biomacromolecules,7(4),1280(2006) |
[6] | D.Y.Zhang,L.M.Qi,Synthesis of mesoporous titania networks consisting of anatase nanowires by templating of bacterial cellulose membranes,Chem.Comm.,2735(2005) |
[7] | D.Dana,B.Vlasta,M.Milan,A.M.Mounir,Investigations of metal-doped titanium dioxide photocatalysts,Appl.Catal.B:Environ.,37(2),91(2002) |
[8] | H.Lachheb,E.Puzenat,A.Houas,M.Ksibi,E.Elaloui,C.Guillard,J.M.Herrmann,Photocatalytic degradation of various types of dyes (Alizarin S,Crocein Orange G,Methyl Red,Congo Red,Methy lene Blue in water by UVirradiated titania,Applied Catalysis B:Environmental,39(1),75(2002) |
[9] | T.R.Rodriguez,S.Vargas,R.Arroyo,R.Moniiel,E.Haro,Modification of the phase transition temperature in titan nia doped with various cations,J.Mater.Res.,12(2),439(1997) |
[10] | S.F.Li,G.L.Ye,G.Q.Chen,Low-temperature preparation and characterization of nanocrystalline anatase TiO2,J.Phys.Chem.C,113(10),4031(2009) |
[11] | Y.H.Zhang,H.X.Zhang,Y.X.Xu,Y.G.Wang,Significant effect of lanthanide doping on the texture and properties of nanocrystalline mesoporous TiO2,Journal of Solid State Chemistry,177(10),3490(2004) |
[12] | P.Harish,D.Anjana,B.Raghunandan,A.Roland,Synthesis of nano-scale TiO2 particles by a nonhydrolytic approach,J.Mater.Chem.,12(6),1625(2002) |
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