基于马氏体相变热力学和亚点阵模型,建立了Fe-C-Mn-Si系合金马氏体相变自由能表达式,并利用Compaq VisualFortran 6软件对其进行编程;应用Thermo-Calc软件及TQ6接口模块并结合大量实验数据,对计算参数进行优化,获得马氏体相变临界驱动力与Fe-C-Mn-Si系合金成分的关系式。采用该方法可较为准确地预测Fe-C-Mn-Si系合金的马氏体转变开始(Ms)温度,并有望推广到更多元合金体系。
Based on martensitic transformation thermodynamics and sublattice model,ΔG γ→M of Fe-C-Mn-Si alloy was deduced and programed by Compaq Visual Fortran 6 software.The parameters of expression were optimized by the aid of TQ6 interface module in Thermo-Calc software combined with experimental results.The relationship between martensitic transformation critical driving force and composition of Fe-C-Mn-Si alloys was obtained.Then Ms temperature of Fe-C-Mn-Si alloys can be accurately predicted by computational method,which can be extended to more complex multicomponent alloy system.
参考文献
[1] | 姜越,康鹏超,尹钟大,朱景川,来忠红.模糊辨识方法预测马氏体不锈钢Ms温度[J].材料热处理学报,2004(03):85-88. |
[2] | 李智超;刘鹏砚;王明罡 .MS点的碳当量计算法[J].辽宁工程技术大学学报(自然科学版),1998,17(03):293-295. |
[3] | 徐祖耀 .Fe-C合金马氏体相变热力学[J].金属学报,1979,15(03):329-338. |
[4] | 徐祖耀 .Fe-X系马氏体相变热力学[J].金属学报,1980,16(04):420-425. |
[5] | 徐祖耀 .Fe-X-C系马氏体相变热力学[J].金属学报,1980,16(04):426-429. |
[6] | 徐祖耀;张鸿冰;罗守福 .Fe-C合金MS的热力学计算及马氏体相变驱动力[J].金属学报,1984,20(03):151-161. |
[7] | 李箭;徐祖耀 .Fe-Ni-C合金马氏体相变驱动力及MS的计算[J].金属学报,1987,23(04):321-328. |
[8] | 张鸿冰;倪乐民;徐祖耀 .Fe-Mn-C系MS及马氏体相变驱动力的热力学计算[J].金属学报,1987,23(01):42-49. |
[9] | 徐祖耀;潘牧 .Fe-Mn-C及Fe-Ni-C合金马氏体相变热力学[J].金属学报,1989,25(04):16-22. |
[10] | Lin LI,P.Wollants,Zuyao XU,B.C.De Cooman,Xiaodong ZHU.Effects of Alloying Elements on the Concentration Profile of Equilibrium Phases in Transformation Induced Plasticity Steel[J].材料科学技术学报(英文版),2003(03):273-277. |
[11] | Lin LI,B.C.De Cooman,P.Wollants,Yanlin HE,Xiaodong ZHOU.Effect of Aluminum and Silicon on Transformation Induced Plasticity of the TRIP Steel[J].材料科学技术学报(英文版),2004(02):135-138. |
[12] | LI Lin,DE COOMAN B C,LIU Ren-dong,VLEUGELS J,ZHANG Mei,SHI Wen.Design of TRIP Steel With High Welding and Galvanizing Performance in Light of Thermodynamics and Kinetics[J].钢铁研究学报(英文版),2007(06):37-41. |
[13] | 何燕霖,李麟,叶平,吴晓春.Thermo-Calc和DICTRA软件系统在高性能钢研制中的应用[J].材料热处理学报,2003(04):73-77. |
[14] | Yanlin HE,Lin LI,Xiaochun WU,Patrick WOLLANTS.Computer Aided Composition Design of Prehardened-Mould Steel for Plastic[J].材料科学技术学报(英文版),2004(01):71-74. |
[15] | HE Yanlin,LI Lin,HUANG Shuigen,Jef Vleugels,Omer Van der Biest.Computer simulation of W-C-Co-V system diffusion couples[J].稀有金属(英文版),2007(05):492-497. |
[16] | Yanlin He;Lin Li;Shuigen Huang .Computer simulating the diffusion behavior of V and W in Co binder layer of WC-Co cemented carbide[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2007(1/2):146-149. |
[17] | Application of thermodynamics and Wagner model on two problems in continuous hot-dip galvanizing[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(5):1399. |
[18] | Huachu L;Wen S;Yanlin H et al.The effect of alloy elements on selective oxidation and galvanizability of TRIP-aided steel[J].Surface and Interface Analysis,2010,42:5-9. |
[19] | 刘华初,何燕霖,李麟.自建数据库在高铝钢组织预测上的应用[J].材料热处理学报,2010(01):160-163. |
[20] | Mats Hillert .The compound energy formalism[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2001(2):161-176. |
[21] | Andersson J O .A thermodynamic evaluation of the Fe-Cr-C system[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1988,19(03):627-636. |
[22] | 李麟;何燕霖;黄水根.[A].深圳:深圳大学出版社,2004 |
[23] | 何燕霖 .高性能预硬型塑料模具钢的计算机合金设计[D].上海大学,2004. |
[24] | Chang H B;Hsu T Y .Thermodynamic prediction of MS and driving force for artensitic transformation in Fe-Mn-C alloys[J].Acta Metallurgica,1986,34(02):333-338. |
[25] | 黄澍,符仁钰,李志峰,李麟.退火温度对C-Mn-P-V高强度TRIP钢组织和力学性能的影响[J].上海金属,2009(06):15-18. |
[26] | 周磊,符仁钰,李志峰,李麟.含铝TRIP钢处理工艺对组织和性能的影响研究[J].上海金属,2010(01):11-14. |
[27] | Kaufman L;Radcliffe S V;Cohen M.Decomposition of Austensite by Siffusional Processes[M].New York:lnterscience Press,1962 |
[28] | Greninger A B .The martensite Thermal arrest in iron-carbon alloys and plain carbon steels[J].Transactions ASM,1942,30:1-26. |
[29] | 赵光伟 .基于Thermo-Calc的多尺度合金凝固传输行为计算机模拟[D].哈尔滨工业大学,2007. |
[30] | 毛兴锋 .工艺参数对低碳微合金高强度双相钢显微组织演变的影响[D].武汉科技大学,2007. |
[31] | M. Zhang;L. Li;R.Y. Fu;D. Krizan;B.C. De Cooman .Continuous cooling transformation diagrams and properties of micro-alloyed TRIP steels[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2006(1/2):296-299. |
[32] | ZHAO Cai,TANG Di,JIANG Hai-tao,ZHAO Song-shan,LI Hui.Process Simulation and Microstructure Analysis of Low Carbon Si-Mn Quenched and Partitioned Steel[J].钢铁研究学报(英文版),2008(04):82-85. |
[33] | M. De MEYER .The Influence of the Substitution of Si by Al on the Properties ofCold Rolled C-Mn-Si TRIP Steels[J].ISIJ International,1999(8):813-822. |
[34] | WANG Xin,KANG Yong-lin,YU Hao,CHEN Li-bin,KONG Qing-fu.Dynamic CCT Diagram of Automobile Beam Steel With High Strength Produced by FTSR Technology[J].钢铁研究学报(英文版),2008(02):60-64. |
[35] | LI Zhuang,WU Di,HU Rong.Austempering of Hot Rolled Si-Mn TRIP Steels[J].钢铁研究学报(英文版),2006(05):41-46. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%