通过包埋工艺在C/C复合材料表面制备了改性SiC涂层.采用Ni-Ti粉末作中间层连结材料,利用真空热压扩散工艺成功制备了SiC涂层改性C/C复合材料与GH3128镍基高温合金的连接样件.借助X射线衍射仪、扫描电子显微镜、能谱分析仪和材料万能试验机,研究了SiC涂层改性C/C复合材料与GH3128镍基高温合金连接接头及其界面的元素分布、微观结构及力学性能.结果表明,在C/C复合材料表面制备SiC涂层,不仅充分改善了C/C复合材料对Ni-Ti中间层连结材料的润湿性,而且还有效缓解C/C复合材料与GH3128连接界面因热膨胀不匹配而造成的热应力.经过SiC涂层改性处理的连接接头,其室温剪切强度可达22.49 MPa；而没有经过SiC涂层改性处理的连接接头,其室温剪切强度几乎为零.
A modified SiC coating was prepared on the surface of C/C composites by a pack cementation process.Ni-Ti mixed powder was used as an interlayer to join SiC coating modified C/C composites and GH3128 Ni-based high-temperature alloy (GH3128) by a vacuum hot-pressing diffusion process.The chemical element distribution,microstructure and mechanical properties of the joint between C/C composites and GH3128 were investigated by X-ray diffractometry,scanning electron microscopy,energy-dispersive spectrometry and material universal testing machine.Results show that the SiC modified coating on the surface of C/C composites not only improves fully the wettability of C/C composites to the Ni-Ti intermediate layer,but also alleviates effectively the thermal stress in the joint due to mismatch thermal expansion.Under the same joining condition,the shear strength of the joint with SiC modified coating at room temperature is up to 22.50 MPa,whereas that of the joint without SiC coating modification is almost 0.
参考文献
| [1] | Fukunage A;Komami T;Ueda S .[J].CARBO,1999,37(09):1087. |
| [2] | Li Ailan;Zeng Xierong;Cao Lamei et al.[J].Materials Review,2003,17(02):26. |
| [3] | 师昌绪.Superalloy 40 Years(高温合金40年)[M].北京:科学出版社,1996 |
| [4] | 周永军,王瑞丹.镍基超合金的发展和研究现状[J].沈阳航空工业学院学报,2006(01):35-37. |
| [5] | 席琛,李贺军,张秀莲.碳/碳复合材料连接工艺的研究进展[J].宇航材料工艺,2003(02):19-21,25. |
| [6] | Singh M;Shpargel TP;Morscher GN;Asthana R .Active metal brazing and characterization of brazed joints in titanium to carbon-carbon composites[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2005(1/2):123-128. |
| [7] | 冀小强,李树杰,马天宇,张艳.用Zr/Nb复合中间层连接SiC陶瓷与Ni基高温合金[J].硅酸盐学报,2002(03):305-310. |
| [8] | Li J L;Xiong J T;Zhang F S .[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2007,483-484:698. |
| [9] | 王标,李克智,李贺军,付前刚,王翔,兰逢涛.包埋浸渗/气相沉积二步法在C/C复合材料表面制备SiC涂层[J].无机材料学报,2007(04):737-741. |
| [10] | Li Hejun;Fu Qiangang;Shi Xiaohong et al.[J].CARBO,2006,44(03):602. |
| [11] | Lan Fengtao;Li Kezhi;Li Hejun et al.[J].Materials Letters,2008,62(15):2347. |
| [12] | 藏晓明 .Study on the Joining of SiC Ceramics and Ni-Based Superalloy by a Composite Interlayer(用复合中间层连接SiC陶瓷和Ni基高温合金)[D].北京:北京航空航天大学,2001. |
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