采用EDTA络合溶胶-凝胶法合成了中温固体氧化物燃料电池的电解质LSGM8282(La0.8Sr0.2Ga0.8-Mg0.2O3-δ)和LSGMF5(La0.8Sr0.2 Ga0.8Mg0.15Fe0.05O3-δ),比较了LSGM8282和LSGMF5的比表面积、交流阻抗谱、电导率、密度、XRD和FT-IR等,研究了Fe掺杂对LSGM8282性能的影响.结果表明,Fe掺杂使LSGM8282离子的电导率由3.62×10-2S/cm提高到5.21×10-2S/cm,致密度由95.13%提高到97.93%.由此可见,Fe的掺杂使LSGM8282的各种性能均得到一定提升,LSGMF5比LSGM8282更适合作中温SOFC电解质材料.
参考文献
[1] | Kim JH.;Yoo HI. .Partial electronic conductivity and electrolytic domain of La0.9Sr0.1Ga0.8Mg0.2O3-delta[J].Solid state ionics,2001(1/2):105-113. |
[2] | Jang JH.;Choi GM. .Partial electronic conductivity of Sr and Mg doped LaGaO3[J].Solid state ionics,2002(Pt.B):481-486. |
[3] | Ishihara T;Ishikawa S;Ando M et al.P02 dependence of valence number of Co in LaGaO3 and its influence on partial electronic and oxide ionic conductivity[J].Solid State Ionics,2004,173(1-4):9. |
[4] | Ishihara T;Matsuda H;Takita Y .Doped LaGaO3 perovskite type oxide as a new oxide iclnic conductor[J].Journal of the American Chemical Society,1994,116(09):3801. |
[5] | Zha Shaowu;Xia Changrong;Fang Xiaohong et al.Processing and electrical properties of doped-LaGaO3 by gelcasting[J].Ceramics International,2001,27(06):649. |
[6] | Ishihara T.;Ishikawa S.;Yu CY.;Akbay T.;Hosoi K.;Nishiguchi H. Takita Y. .Oxide ion and electronic conductivity in Co doped La0.8Sr0.2Ga0.8Mg0.2O3 perovskite oxide[J].Physical chemistry chemical physics: PCCP,2003(11):2257-2263. |
[7] | Ishihara Tatsumi .Solid oxide fuel cell using Co doped La(Sr)Ga(Mg)O_3 perovskite oxide with notably high power density at intermediate temperature[J].Chemical communications,1999(13):1227-1228. |
[8] | Huang KQ.;Goodenough JB. .Wet chemical synthesis of Sr- and Mg-doped LaGaO3, a perovskite-type oxide-ion conductor[J].International Journal of Quantum Chemistry,1998(2):274-283. |
[9] | A. Cüneyt Tas;Peter J. Majewski .Chemical Preparation of Pure and Strontium-and/or Magnesium-Doped Lanthanum Gallate Powders[J].Journal of the American Ceramic Society,2000(12):2954-2960. |
[10] | Majewski P;Rozumek M;Tas C A et al.Processing of(La,Sr)(Ga,Mg)O3 solid electrolyte[J].Journal of Electroceramics,2002,8:65. |
[11] | Stevenson JW.;Mccready DE.;Pederson IR.;Weber WJ.;Armstrong TR. .PROCESSING AND ELECTRICAL PROPERTIES OF ALKALINE EARTH-DOPED LANTHANUM GALLATE[J].Journal of the Electrochemical Society,1997(10):3613-3620. |
[12] | 曹敏,徐国跃,周健,周勇辉,凌栋.EDTA-硝酸盐法制备La0.8Sr0.2Ga0.85Mg0.15O3-δ及其性能[J].硅酸盐通报,2006(01):101-104. |
[13] | Bauerle J E .Study of solid electrolyte polarization by a cornplex admittance method[J].Journal of Physics and Chemistry of Solids,1969,30(12):2657. |
[14] | 徐国跃,曹敏,刘波,承新,周健.改进的柠檬酸法制备LSGM和LSGMC8.5及其性能比较[J].无机材料学报,2006(03):612-618. |
[15] | 尧巍华,唐子龙,张中太,罗绍华,李杰,谭强强.La0.9Sr0.1Ga0.8Mg0.2O2.85固体电解质合成及其性能[J].稀有金属材料与工程,2004(03):297-299. |
[16] | Ishihara T;Furutani H;Honda M et al.Improved oxide ion conductivity in La0.8Sr0.2Ga0.8Mg0.2O3 by doping Co[J].CHEMISTRY OF MATERIALS,1999,11(08):2081. |
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