以羧甲基纤维素的水溶液为反应介质制备了快速响应的温度敏感性聚(N-异丙基丙烯酰胺)水凝胶.利用DSC对其相转变温度进行了表征,并测定了不同温度下达到平衡时水凝胶的溶胀比,研究了水凝胶的去溶胀动力学.结果表明,在聚合/交联过程中羧甲基纤维素的存在对PNIPA水凝胶的相转变温度几乎没有影响;与传统水凝胶相比,该水凝胶的溶胀性能有所提高,并且具有较快的响应速率.
参考文献
[1] | Heskins M;Guillet J E .[J].Journal of Macromolecular Science:Chemistry,1968,A2:1441-1455. |
[2] | Schikd H G .[J].Progress in Polymer Science,1992,17:163-249. |
[3] | Kabra B G;Gehrke S H .[J].Polymer Communications,1991,32:322-323. |
[4] | Wu X S;Hoffman A S;Yager P .[J].Journal of Polymer Science Part A:Polymer Chemistry,1992,30:2121-2129. |
[5] | Yoshida R;Uchida K;Kaneko Y et al.[J].NATURE,1995,374:240-242. |
[6] | Kaneko Y.;Kikuchi A.;Yoshida R.;Sakurai Y.;Okano T.;Sakai K. .INFLUENCE OF FREELY MOBILE GRAFTED CHAIN LENGTH ON DYNAMIC PROPERTIES OF COMB-TYPE GRAFTED POLY(N-ISOPROPYLACRYLAMIDE) HYDROGELS[J].Macromolecules,1995(23):7717-7723. |
[7] | Cheng S X;Zhang J T;Zhuo R X .[J].Journal of Biomedical Materials Research,2003,67A:96-103. |
[8] | Zhang JT.;Cheng SX.;Huang SW.;Zhuo RX. .Temperature-sensitive poly (N-isopropylacrylamide) hydrogels with macroporous structure and fast response rate[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2003(7):447-451. |
[9] | Baw Y H;Okano T;Kim S W.[J].Macromolecular Rapid Communications,1988(09):185-189. |
[10] | Zhang XZ.;Zhuo RX. .Synthesis of temperature-sensitive poly(N-isopropylacrylamide) hydrogel with improved surface property[J].Journal of Colloid and Interface Science,2000(2):311-313. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%