采用溶胶凝胶法以硅酸铝纤维布(fiber)为载体通过不同溶胶配比制备纳米TiO2-硅酸铝纤维(TiO2-fiber)复合物.使用X射线衍射仪(XRD)及场发射扫描电镜(FSEM)等手段对其进行表征;在波长为253.7nm的紫外光(UV)照射下使用复合物进行多种工况下的光催化脱汞试验,验证催化脱汞性能.结果表明,复合物表面TiO2纳米微粒尺寸可控制在10~20nm左右;紫外光照射下脱汞率最高可达95%,催化脱汞性能优异;溶胶醇酸比为2/1时,复合物催化活性最强;气氛组分、光照强度及温度等因素对催化反应有明显影响.
参考文献
[1] | John H.Pavlish;Everett A.Sondreal;Michael D.Mann;Edwin S.Olson;Kevin C.Galbreath;Dennis L.Laudal;Steven A.Benson .Status review of mercury control options for coal-fired power plants[J].Fuel Processing Technology,2003(2/3):89-165. |
[2] | Brown TD;Hargis RA Jr;O'Dowd WJ;Smith DN .Mercury Measurement and Its Control: What We Know, Have Learned, and Need to Further Investigate[J].Journal of the Air & Waste Management Association,1999(6):628-640. |
[3] | Erik Pitoniak;Chang-Yu Wu;Danielle Londeree;David Mazyck;Jean-Claude Bonzongo;Kevin Powers;Wolfgang Sigmund .Nanostructured silica-gel doped with TiO_2 for mercury vapor control[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,2003(3/4):281-292. |
[4] | Vidic Radisav D. .Vapor-phase elemental mercury adsorption by activated carbon impregnated with chloride and chelating agents[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(1):3-14. |
[5] | Erik Pitoniak;Chang-Yu Wu;Danielle Londeree;David Mazyck;Jean-Claude Bonzongo;Kevin Powers;Wolfgang Sigmund .Nanostructured silica-gel doped with TiO_2 for mercury vapor control[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,2003(3/4):281-292. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%