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由于镁及其合金具有良好的生物相容性和力学相容性,降低镁合金过快的腐蚀速度成为其作为生物材料应用的关键,医用镁合金表面改性已成为新一代生物材料的研究重点.介绍医用镁合金的发展历程,重点讨论镁合金表面生物活性陶瓷(如羟基磷灰石(HA))、阳极氧化膜、可降解高分子聚合物(如聚乳酸(PLA)、PLGA、壳聚糖)、惰性生物陶瓷涂层(如TiO2、Al2O3、ZrO2)、化学转化膜(氟化膜、稀土转化膜)和金属镀层(如Ti、Zn)制备、耐蚀性及其生物相容性,并指出其发展趋势.

参考文献

[1] Bruno Zberg;Peter J. Uggowitzer;Jorg F. Loffler .MgZnCa glasses without clinically observable hydrogen evolution for biodegradable implants[J].Nature materials,2009(11):887-891.
[2] HENCH L L;POLAK J M .Third-generation biomedical materials[J].Science,2002,295(5557):1014-1027.
[3] Rongchang Zeng;Wolfgang Dietzel;FrankWitte;Norbert Hort;Carsten Blawert .Progress and Challenge for Magnesium Alloys as Biomaterials[J].Advanced Engineering Materials,2008(8):B3-B14.
[4] Staiger MP;Pietak AM;Huadmai J;Dias G .Magnesium and its alloys as orthopedic biomaterials: A review[J].Biomaterials,2006(9):1728-1734.
[5] HEUBLEIN B;ROHDE R;NIEMEYER M;KAESE V,HARTUNG W,R(O)CKEN C,HAUSDORF G,HAVERICH A.Degradation of magnesium alloys:A new principle in cardiovascular implant technology[A].New York,1999:5-10.
[6] Heinz Haferkamp;Rudolf Boehm;Uwe Holzkamp .Alloy Development, Processing and Applications in Magnesium Lithium Alloys[J].Materials transactions,2001(7):1160-1166.
[7] Witte F;Kaese V;Haferkamp H;Switzer E;Meyer Lindenberg A;Wirth CJ;Windhagen H .In vivo corrosion of four magnesium alloys and the associated bone response.[J].Biomaterials,2005(17):3557-3563.
[8] 李龙川,高家诚,王勇.医用镁合金的腐蚀行为与表面改性[J].材料导报,2003(10):29-32.
[9] Guangling Song;Shizhe Song .A Possible Biodegradable Magnesium Implant Material[J].Advanced Engineering Materials,2007(4):298-302.
[10] 高家诚,乔丽英.镁基可降解硬组织生物材料的研究进展[J].功能材料,2008(05):705-708.
[11] Frank Wittea;Norbert Hort;Carla VOgt;Smadar Cohen;Karl Ulrich Kainer;Regine Willumeit;Frank Feyerabend .Degradable biomaterials based on magnesium corrosion[J].Current opinion in solid state & materials science,2008(5/6):63-72.
[12] 黄晶晶,杨柯.镁合金的生物医用研究[J].材料导报,2006(04):67-69.
[13] 陶海荣,蒋垚.可降解镁合金内固定材料研究进展[J].国际骨科学杂志,2008(05):293-294,312.
[14] 郑玉峰,刘彬,顾雪楠.可生物降解性医用金属材料的研究进展[J].材料导报,2009(01):1-6.
[15] 张佳,宗阳,付彭怀,袁广银,丁文江.镁合金在生物医用材料领域的应用及发展前景[J].中国组织工程研究与临床康复,2009(29):5747-5750.
[16] Witte F;Fischer J;Nellesen J;Crostack HA;Kaese V;Pisch A;Beckmann F;Windhagen H .In vitro and in vivo corrosion measurements of magnesium alloys[J].Biomaterials,2006(7):1013-1018.
[17] Witte F;Feyerabend F;Maier P;Fischer J;Stormer M;Blawert C;Dietzel W;Hort N .Biodegradable magnesium-hydroxyapatite metal matrix composites.[J].Biomaterials,2007(13):2163-2174.
[18] Gu X;Zheng Y;Cheng Y;Zhong S;Xi T .In vitro corrosion and biocompatibility of binary magnesium alloys.[J].Biomaterials,2009(4):484-498.
[19] AGHION E E;ARNON A;ATAR D;SEGAL G .Biodegradable magnesium alloys and uses thereof[P].US,PCT/IL2007/000520,2007-08-11.
[20] 洪岩松,杨柯,张广道,黄晶晶,郝玉全,艾红军.可降解镁合金的动物体内骨诱导作用[J].金属学报,2008(09):1035-1041.
[21] ERINC M;SILLEKENS W;MANNENS R.Applicability of existing magnesium alloys as biomedical implant materials[A].Warrendale:TMS,2009:209-214.
[22] ZENG R C;ZHANG R F;CHEN R S;DIETZEL W,KAINER U K.Corrosion of plasma electrolytic oxidation coatings on Mg-Ca alloy in Hank's solutions[A].Weinheim:Wiley-VCH,2009:961-966.
[23] 张春艳,曾荣昌,陈君,杨惠,田中青.镁合金AZ31表面液相沉积Ca-P生物陶瓷涂层的研究[J].稀有金属材料与工程,2009(08):1363-1367.
[24] Chun-Yan, Z.;Rong-Chang, Z.;Cheng-Long, L.;Jia-Cheng, G. .Comparison of calcium phosphate coatings on Mg-Al and Mg-Ca alloys and their corrosion behavior in Hank's solution[J].Surface & Coatings Technology,2010(21/22):3636-3640.
[25] 郭磊,刘魁,张世亮,高晓宇,黄晶晶,杨柯.CA-P/AZ31B镁合金的生物相溶性研究[J].稀有金属材料与工程,2009(01):99-103.
[26] 耿芳,谭丽丽,贺永莲,杨敬玉,张炳春,杨柯.多孔镁表面生物活性β-TCP涂层的制备及其细胞相容性研究[J].稀有金属材料与工程,2009(02):318-322.
[27] 高亚丽,熊党生,王存山,潘学民.医用镁合金激光熔覆羟基磷灰石涂层初探[J].特种铸造及有色合金,2009(04):305-307.
[28] Y.W. Song;D.Y. Shan;E.H. Han .Electrodeposition of hydroxyapatite coating on AZ91D magnesium alloy for biomaterial application[J].Materials Letters,2008(17/18):3276-3279.
[29] CHEN Jun,ZENG Rong-chang,HUANG Wei-jiu,ZHENG Zi-qing,WANG Zhen-lin,WANG Jun.Characterization and wear resistance of macro-arc oxidation coating on magnesium alloy AZ91 in simulated bedy fluids[J].中国有色金属学会会刊(英文版),2008(z1):361-364.
[30] Zhang XP;Zhao ZP;Wu FM;Wang YL;Wu J .Corrosion and wear resistance of AZ91D magnesium alloy with and without microarc oxidation coating in Hank's solution[J].Journal of Materials Science,2007(20):8523-8528.
[31] Guangling Song .Control of biodegradation of biocompatable magnesium alloys[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2007(4):1696-1701.
[32] 许鑫华,程静,张春怀,闫学良,朱天兵,姚康德,曹路,刘寅.医用镁合金的生物腐蚀及高分子涂层处理[J].稀有金属材料与工程,2008(07):1225-1228.
[33] 赵常利,张绍翔,何慈晖,李佳楠,张蓓蕾,张小农.生物医用镁合金表面PLGA涂层研究[J].功能材料,2008(06):987-989,993.
[34] 张萌,齐民,刘洪泽,杨璠,赵红,杨大智,刘炼.聚丙交酯-乙交酯聚合物(PLGA)涂层体外降解行为研究[J].功能材料,2006(02):277-280.
[35] 黄晶晶,任伊宾,张炳春,杨柯.可降解镁植入材料表面涂层的制备及其性能[J].中国有色金属学报,2007(09):1465-1469.
[36] ZENG R C;CHEN J;DIETZEL W;HORTK N KAINER K U .Electrochemical behavior of magnesium alloys in simulated body fluids[J].Transactions of Nonferrous Metals Society of China,2007,17(z1):s166-s169.
[37] Witte F;Fischer J;Nellesen J;Vogt C;Vogt J;Donath T;Beckmann F .In vivo corrosion and corrosion protection of magnesium alloy LAE442.[J].Acta biomaterialia,2010(5):1792-1799.
[38] 颜廷亭,谭丽丽,熊党生,龚明明,张炳春,杨柯.生物医用AZ31B镁合金表面稀土转化膜的制备及其性能研究[J].稀有金属材料与工程,2009(05):918-923.
[39] Yizao Wan;Guangyao Xiong;Honglin Luo;Fang He;Yuan Huang;Xiaoshong Zhou .Preparation and characterization of a new biomedical magnesium-calcium alloy[J].Materials & design,2008(10):2034-2037.
[40] Chenglong Liu;Yunchang Xin;Xiubo Tian;J. Zhao;Paul K. Chu .Corrosion resistance of titanium ion implanted AZ91 magnesium alloy[J].Journal of Vacuum Science & Technology, A. Vacuum, Surfaces, and Films,2007(2):334-339.
[41] ZENG R C;DIETZEL W;CHEN J;HUANG W J WANG J .Corrosion behavior of TiO2 coating on magnesium alloy AM60 in Hank's solution[J].Key Engineering Materials,2008,373/374:609-612.
[42] 谈国强;苗鸿雁;宁青菊;夏傲.生物陶瓷材料[M].北京:化学工业出版社,2006:84-86.
[43] Yang, JX;Jiao, YP;Cui, FZ;Lee, IS;Yin, QS;Zhang, Y .Modification of degradation behavior of magnesium alloy by IBAD coating of calcium phosphate[J].Surface & Coatings Technology,2008(22/23):5733-5736.
[44] 高家诚,李龙川,王勇.镁表面改性及其在仿生体液中的耐蚀行为[J].中国有色金属学报,2004(09):1508-1513.
[45] Liying Qiao;Jiacheng Gao;Yong Wang;Sali Wang;Sha Wu;Yan Xue .Biocompatibility Evaluation of Magnesium-based Materials[J].Materials Science Forum,2007(1):459-462.
[46] 郭磊,刘魁,张世亮,黄晶晶,谭丽丽,杨柯.氧化镁膜AZ31B镁合金材料的细胞毒性研究[J].稀有金属材料与工程,2008(06):1027-1031.
[47] 沈新元.生物医学纤维及其应用[M].北京:中国纺织出版社,2009:132-144.
[48] 曾荣昌,兰自栋,陈君,莫鲜花,韩恩厚.镁合金表面化学转化膜的研究进展[J].中国有色金属学报,2009(03):397-404.
[49] HASSEL T;BACH F W;KRAUSE C;WILK P.Corrosion protection and repassivation after the deformation of magnesium alloys coated with a protective magnesium flouride layer[A].San Francisco:TMS,2005:485-491.
[50] Amy L. Rudd;Carmel B. Breslin;Florian Mansfeld .The corrosion protection afforded by rare earth conversion coatings applied to magnesium[J].Corrosion Science,2000(2):275-288.
[51] Jiacheng Gao;Yan Xue;Liying Qiao;Yong Wang;Yan Zhang .Surface Modification of Magnesium with Rare Earth Conversion Films for Biomedical Protection[J].Materials Science Forum,2007(1):601-604.
[52] ZHANG Er-lin;XU Li-ping;YANG Ke .Formation by ion plating of Ti-coating on pure Mg for biomedical applications[J].Scripta Materialia,2005,53(05):523-527.
[53] Xin YC;Liu CL;Zhang WJ;Jiang J;Guoyi TY;Tian XB;Chua PK .Electrochemical behavior Al2O3/Al coated surgical AZ91 magnesium alloy in simulated body fluids[J].Journal of the Electrochemical Society,2008(5):C178-C182.
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