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Raman spectra of the PbTiO3 films via sol-gel process were investigated by using a Jobin Yvon U1000 system. Compared with the Raman spectra of the PbTiO3 single crystals, Raman peaks of PbTiOs films shift downward, which is attributed to the stress effect in the PbTiO3 films exerted by the substrate and the size effect on the Raman frequencies

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