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以Ca(H_2P0_4)_2·H_2O粉末和H_3PO_4水溶液合成的无机复合质子膜作为电解质,制备低温燃料电池,评价了无机质子膜的质子传导率以及所制成的燃料电池的输出性能.结果表明,在80℃、70%RH条件下,其质子传导率可以达到3.5×10~(-2) S/cm,所制成的燃料电池在60℃时输出功率达到11.5mW/cm~2.

The fuel cell,operating at low temperatures is prepared using the inorganic composite membrane as the electrolyte,is synthesized with CCa(H_2P0_4)_2/·H_2O powders and H_3PO_4 solution.The proton conductivity of the composite membrane and the output properties of the prepared fuel cell are measured,As a result,the inorganic composite membrane shows a proton conductivity of 3.5×10~(-2)S/cm at 80℃ and 70 % RH,and the prepared fuel cell releases an output power of 11.5mW/cm~2 at 60℃.

参考文献

[1] 衣宝廉.燃料电池--原理@技术@应用[M].北京:化学工业出版社,2003:161.
[2] Steele B C H;Heinzel A .Materials for fuel-cell technologies[J].Nature,2001,414(6861):345.
[3] Li Haibin;Toyoki Kunitake .Efficient proton conduction of nanometer-thick film of porous silica as prepared by oxygen plasma treatment[J].Microporous and Mesoporous Materials,2006,97(1-3):42.
[4] F.M.Vichi;M.T.Colomer .Nanopore Ceramic Membranes as Novel Electrolytes for Proton Exchange Membranes[J].Electrochemical and solid-state letters,1999(7):313-316.
[5] Yusuke DAIKO;Tomoko AKAI;Toshihiro KASUGA .Remarkable High Proton Conducting P_2O_5-SiO_2 Glass as a Fuel Cell Electrolyte Working at Sub-Zero to 120 deg C[J].日本セラミックス协会学术论文志,2001(1274):815-817.
[6] Toshihiro Kasuga;Masashi Nakano;Masayuki Nogami .Fast Proton Conductors Derived from Calcium Phosphate Hydrogels[J].Advanced Materials,2002(20):1490-1492.
[7] Nogami M.;Goto Y.;Kasuga T.;Matsushita H. .A sol-gel-derived class as a fuel cell electrolyte[J].Advanced Materials,2000(18):1370-1372.
[8] Klaus-Dieter Kreuer .Proton Conductivity: Materials and Applications[J].Chemistry of Materials,1996(3):610-641.
[9] Felix N Btichi;Günther G Scherer .In-situ resistance measurements of Nafion 117 membranes in polymer electrolyte fuel cells[J].Journal of Electroanalytical Chemistry,1996,404(01):37.
[10] Kohei Uosaki;Kentaro Okazaki;Hideaki Kita .Conductivity of Nation membranes at low temperatures[J].Journal of Electroanalytical Chemistry,1990,287(01):163.
[11] Haile S M;Boysen D A;Chisholm C R I et al.Solid acids as fuel cell electrolytes[J].Nature,2001,410(6831):910.
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