利用紫外老化试验箱对三元乙丙橡胶(EPDM)进行人工加速老化试验,采用色度计、光泽度仪、电子万能试验机和傅立叶变换红外光谱仪研究了人工气候老化对EPDM的颜色、光泽度、力学性能和化学结构的影响.结果表明,老化初期EPDM表面颜色随老化时间的延长逐渐变黄变亮,光泽度增加,18天后色差变化很小,光泽度开始下降.老化过程中发生交联反应,拉伸强度随老化时间的延长和交联密度的增加而增大.红外光谱显示有>C=O和C-O-C的生成,说明在紫外人工气候条件下,EPDM的降解产物为羰基化物和醚或酯.
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