欢迎登录材料期刊网

材料期刊网

高级检索

采用铝诱导非晶硅薄膜晶化技术制备了多晶硅薄膜,并研究了多晶硅的成核和生长特性。非晶硅薄膜采用等离子体增强化学气相沉积法制备,其表面沉积铝薄膜后经不同温度的氮氛围退火处理。结果表明,退火后的硅薄膜层与铝层发生置换,所生长的多晶硅颗粒的平均尺寸约为150nm。X射线衍射分析结果揭示,薄膜的晶向显著依赖于退火温度,较低温度下,铝诱导晶化速率较慢,薄膜的优化晶向与非晶硅薄膜中团簇的初始原子排列趋势紧密相关。而较高温度下,铝诱导晶化促使多晶硅(111)择优成核及随后的固相生长。

Polycrystalline silicon(poly-Si) films were prepared from amorphous silicon(a-Si) films by aluminum-induced crystallization(AIC) method,and the nucleation and growth mechanism of the poly-Si films was studied.Amorphous silicon(a-Si) films were deposited on glass substrate by plasma enhanced chemical vapor deposition(PECVD),and then annealed in N2 atmosphere at different temperatures after aluminum(Al) layer was sputtered on a-Si film's surface.The results show that the film sequence of Si layer and Al layer was exchanged after annealing,and the average grain size of the poly-Si was about 150 nm.X-ray diffraction results reveal that the film's crystal orientation was particularly dependent on the annealing temperature.At the low temperature,the AIC speed was at a lower level,and the crystal orientation was related on atom arrangement trend of the a-Si film's initial cluster.While at high temperature,the AIC played a key role on preferential nucleation of the poly-Si(111) and the subsequent solid phase growth process.

参考文献

[1] Nast O.;Koschier LM.;Sproul AB.;Wenham SR.;Puzzer T. .Aluminum-induced crystallization of amorphous silicon on glass substrates above and below the eutectic temperature[J].Applied physics letters,1998(22):3214-3216.
[2] Schneider J;Schneider A;Sarikov A;Klein J;Muske M;Gall S;Fuhs W .Aluminum-induced crystallization: Nucleation and growth process[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2006(9/20):972-975.
[3] 张世斌,廖显伯,安龙,杨富华,孔光临,王永谦,徐艳月,陈长勇,刁宏伟.非晶/微晶过渡区域硅薄膜的微区喇曼散射研究[J].物理学报,2002(08):1811-1815.
[4] 黄添懋,陈诺夫,张兴旺,白一鸣,尹志岗,施辉伟,张汉,汪宇,王彦硕,杨晓丽.铝诱导结晶法制备高度(111)择优取向多晶硅薄膜及成核分析[J].中国科学E辑,2010(11):1378-1382.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%