采用光学显微镜、扫描电镜、X射线衍射、透射电镜以及滑动磨损实验,研究了500℃时效35h处理对激光熔覆Fe901/3%Cu涂层组织结构及性能的影响.结果表明,未经过时效处理的熔覆层主要是由α-Fe(马氏体),M_7C_3和M_(23)C_6构成,并且α-Fe存在(110)晶面的择优取向,在马氏体上分布着高密度的位错,而且位错沿着熔覆基材向熔覆层方向延伸分布.熔覆层经过500℃时效35h以后,熔覆层中富铬碳化物相的相对含量有所增加,并且沿M_7C_3相由马氏体中析出弥散分布的ε-Cu颗粒,在ε-Cu颗粒附近分布有若干位错,对位错起钉扎作用.熔覆层在时效以后的剖面显微硬度和表面耐磨性能显著提高.
The effects of aging at 500℃ for 35h on microstructure and properties of Fe901/3%Cu laser clad coating were investigated by means of optical microscope, scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), and sliding wear teat. It is found that α-Fe (martensite) is presented accompanied by M_7C_3 and M_(23)C_6 in the as-clad coating. The preferred direction at (110)crystal plane exists in the α-Fe matrix. TEM observation shows that high density dislocations exist in the martensite. The dislocations distribute in the direction from substrate to clad coating. The dispersed Cr-rich carbide and ε-Cu precipitate from martensite when the clad coating is aged at 500℃ for 35h. The microhardness and wear resistance increase greatly after the aging treatment.
参考文献
[1] | Bourithis L;Papadimitriou G .Bonding a plain carbon steel with the plasma transferred arc process using boron and chromium diboride powders:microstructure and wear properties[J].Materials Letters,2003,57(12):1835-1839. |
[2] | Corbin SF.;Toyserkani E.;Khajepour A. .Cladding of an Fe-aluminide coating on mild steel using pulsed laser assisted powder deposition[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2003(1/2):48-57. |
[3] | Dawen Zeng;K.C. Yung;Changsheng Xie .INVESTIGATION OF CORROSION BEHAVIOR OF HIGH NICKEL DUCTILE IRON BY LASER SURFACE ALLOYING WITH COPPER[J].Scripta materialia,2001(12):2747-2752. |
[4] | 王军,武晓雷,洪友士.铁基合金激光熔覆涂层的高温回火组织及其磨损性能[J].钢铁研究学报,2000(03):51-54. |
[5] | Gatto A;Bassoli E;Fornari M .Plasma Transferred Arc deposition of powdered high performances alloys: process parameters optimisation as a function of alloy and geometrical configuration[J].Surface & Coatings Technology,2004(2/3):265-271. |
[6] | d'Oliveira ASCM.;Vilar R.;Feder CG. .High temperature behaviour of plasma transferred arc and laser Co-based alloy coatings[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2002(1/4):154-160. |
[7] | 张锦英,马明星,刘文今,钟敏霖,张伟明,张红军.钒、钛对激光熔覆铁基原位生成颗粒增强复合涂层组织的影响[J].金属热处理,2003(08):1-4. |
[8] | Herrera Y;Crigorescu I C;Ramirez J et al.Microstnictural characterization of vanadium carbide laser clad coatings[J].Surface and Coatings Technology,1998,108-109(1-3):308-311. |
[9] | Y. Isshiki;K. Mizumoto;M. Hashimoto .Synthesis of iron-tungsten alloy on mild steel by laser surface alloying[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1998(1/2):468-470. |
[10] | Chen Q;Jin Z P .The Fe-Cu system:A thermodynainic evaluation[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1995,26(02):417-426. |
[11] | 毛卫民,任慧平,余永宁.结构钢中含铜析出相的时效强化作用[J].材料热处理学报,2004(02):1-4. |
[12] | 钟平,刘建华,于刚,王俊丽.时效对0Cr15Ni5Cu2Ti钢组织与性能的影响[J].材料热处理学报,2006(01):58-62. |
[13] | Fazal;Khalid A .Copper precipitation in M_(23)C_6 grain boundary carbides in alloy steel[J].Scripta Materialia,2001,44(05):797-801. |
[14] | H(a)ttestrand M;Andren H O .Microstnictural development during ageing of an 11 % chromium steel alloyed with copper[J].Materials Science and Engineering A,2001,318(1-2):94-101. |
[15] | 张永权;刘天军;杨才富 .铜的时效行为及其对06NiCuCrMoNb钢力学性能的影响[J].钢铁研究学报,1998,10(04):41-45. |
[16] | Hou QY;Gao JS;Zhou F .Microstructure and wear characteristics of cobalt-based alloy deposited by plasma transferred arc weld surfacing[J].Surface & Coatings Technology,2005(2/3):238-243. |
[17] | 侯清宇,高甲生.Co-Cr-W系等离子弧堆焊合金层显微结构的研究[J].稀有金属材料与工程,2004(11):1199-1202. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%