化学交联是提高质子交换膜性能的一种有效方法.交联质子交换膜具有较低的水溶胀性、甲醇渗透性,以及较高的热、力学稳定性.使用化学交联法制备质子交换膜时,通常采用交联聚合物磺化法、磺化聚合物交联法和共混聚合物交联法等三种方法.采用不同方法交联时,交联活性点的选取各不相同,制备的交联质子交换膜性能也有差异.深入研究交联程度、离子交换容量、交联剂种类等不同制备条件对交联膜的微观结构及性能的影响,才能使交联质子交换膜的综合性能得到优化.
参考文献
| [1] | 吴洪,王宇新,王世昌.用于聚合物电解质膜燃料电池中的质子导电膜[J].高分子材料科学与工程,2001(04):7-11. |
| [2] | Rikukawa M;Sanui K .[J].Progress in Polymer Science,2000,25:1463-1502. |
| [3] | Alelio G D' .Ion exchanger[P].US 2366007,1944. |
| [4] | Jin-Li Q;Yoshimoto N;Ishikawa M et al.[J].Electrochimica Acta,2002,47:3441-3446. |
| [5] | Jin-Li Q;Yoshimoto N;Ishikawa M .[J].Journal of Power Sources,2002,105:45-51. |
| [6] | Przyluski J;Poltarzewski Z;Ieczorek W .[J].Polymer,1997,39:4343-4347. |
| [7] | Yamaki T;Asano M;Maekawa Y et al.[J].Radiation Physics and Chemistry,2003,67:403-407. |
| [8] | M M Nasef;H Saidi .[J].Journal of Membrane Science,2003,216:27-38. |
| [9] | Yamaki T;Kobayashi K;Asano M;Kubota H;Yoshida M .Preparation of proton exchange membranes based on crosslinked polytetrafluoroethylene for fuel cell applications[J].Polymer: The International Journal for the Science and Technology of Polymers,2004(19):6569-6573. |
| [10] | Chen N;Hong L .[J].Solid State Ionicis,2002,146:377-385. |
| [11] | Manea C;Mulder M .[J].Desalination,2002,146:287-291. |
| [12] | Yen S P S;Narayanan S R;Halpert G et al.[P].US 5795496,1998. |
| [13] | Mao S S;Hamrock S J;Ylitalo D A .[P].US 6090895,2000. |
| [14] | Nolte R;Ledjeff K;Bauer M et al.[J].Journal of Membrane Science,1993,83:211-220. |
| [15] | Kaur S;Florio G;Michalak D .[J].POLYMER,2002,43:5163-5167. |
| [16] | Mikhailenko S D;Wang K;Kaliaguine S et al.[J].Journal of Membrane Science,2004,233:93-99. |
| [17] | Kerres J;Cui W;Schnurnberger W .[P].DP 196 22337.7,1997. |
| [18] | Kerres J;Zhang W;Cui W .[J].J Polym Sci :Part A:Polym Chem,1998,36:1441-1448. |
| [19] | Kerres J.;Junginger M.;Cui W. .Development and characterization of crosslinked ionomer membranes based upon sulfinated and sulfonated PSU - Crosslinked PSU blend membranes by alkylation of sulfinate groups with dihalogenoalkanes[J].Journal of Membrane Science,1998(2):227-241. |
| [20] | Guo Q;Pintauro P N;Yang H et al.[J].Journal of Membrane Science,1999,154:175-181. |
| [21] | Rhim J;Park H B;Lee C et al.[J].Journal of Membrane Science,2004,238:143-151. |
| [22] | Metayer M;Ould C;Bareck M' .[J].Reactive & Functional Polymers,1997,33:311-321. |
| [23] | Kang M;Choi Y;Moon S .[J].Journal of Membrane Science,2002,207:157-170. |
| [24] | Chen S;Krishnan L;Srinivasan S et al.[J].Journal of Membrane Science,2004,243:327-333. |
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