基于浸渍法制备得到磷钨酸均匀负载在五乙烯六胺修饰ZrSBA-15的多酸基催化材料；并借助XRD、N2-吸附/脱附等温线、FT-IR、TEM等测试手段对其结构进行了系统表征。以H2 O2作为氧化剂，所合成的多酸基复合材料在二苯并噻吩氧化反应中呈现优异催化性能，经6次循环使用后催化性能未有明显降低。
A layer-by-layer stabilization strategy was employed to immobilize active tungstophosphoric acid onto pentaethylenehexamine-preloaded ZrSBA-15. The synthesized materials were characterized by XRD, N2 adsorption-desorpton isotherms, FT-IR and TEM, etc. Utilizing hydrogen peroxide as oxidant, the composite exhibited favorable performance toward the deep oxidation desulfurization of dibenzothiophene;and it could be reused at least six runs without discernible decrease in activity.
参考文献
| [1] | Shih-Yuan Chen;Chih-Yuan Tang;Wei-Tsung Chuang.A Facile Route to Synthesizing Functionalized Mesoporous SB A-15 Materials with Platelet Morphology and Short Mesochannels[J].Chemistry of Materials: A Publication of the American Chemistry Society,200812(12):3906-3916. |
| [2] | Ling-Yan Meng;Shang-Ru Zhai;Shi Li;Bin Zhai;Qing-Da An;Xiao-Wei Song.Synthesis and Characterization of Tungstophosphoric Acid/Pentaethylenehexamine/ZrSBA-15 and Its Use in the Selective Oxidation of Benzyl Alcohol under Solvent-Free Conditions[J].European journal of inorganic chemistry,201414(14):2337-2344. |
| [3] | Meng, Lingyan;Zhai, Shangru;Sun, Zuchen;Zhang, Feng;Xiao, Zuoyi;An, Qingda.Green and efficient synthesis of adipic acid from cyclohexene over recyclable H3PW4O24/PEHA/ZrSBA-15 with platelet morphology[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2015:123-130. |
| [4] | Barbara Pawelec;Rufino M. Navarro;Jose Miguel Campos-Martin.Towards near zero-sulfur liquid fuels: a perspective review[J].Catalysis science & technology,20111(1):23-42. |
| [5] | Vincent Lam;Guangchun Li;Chaojie Song.A review of electrochemical desulfurization technologies for fossil fuels[J].Fuel Processing Technology,2012:30-38. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%