研究了复合烧结助剂ZnO-B2O3-SiO2(ZBS)玻璃和LiF添加量对Ca0.6La0.8/3TiO3-Li0.5Nd0.5 TiO3(CLLNT)陶瓷相结构、烧结特性及介电性能的影响.加入复合烧结助剂(ZBS玻璃和LiF)后,CLLNT陶瓷的烧结温度从1400℃降至1000℃;当ZBS玻璃的添加量为4%(质量分数,下同)、LiF的添加量小于3%时,CLLNT陶瓷样品中没有发现第二相,主晶相仍为斜方钙钛矿结构;当ZBS玻璃的添加量为4%、LiF的添加量为1%时,CLLNT陶瓷在1000℃烧结3h获得最佳性能,介电常数εr=97,Q×f=1286GHz,TCF=43×10-6/℃(4GHz).
参考文献
[1] | 杨辉,张启龙,王家邦,尤源,黄伟.微波介质陶瓷及器件研究进展[J].硅酸盐学报,2003(10):965-973,980. |
[2] | Huang Chengliang et al.Dielectric properties of(1-y)Ca1-xLa2x/3TiO3-yNd1/2 Li1/2 TiO3 ceramic system at microwave frequency[J].Materials Research Bulletin,2001,36:547. |
[3] | Takahashi H;Baba Y;Ezaki K et al.Dielectric characteristics of(A1+1/2@A3+1/2)TiO3 ceramics at microwave frequencies tics of(A1+1/2@A3+1/2)TiO3 ceramics at microwave frequencies[J].Journal of Applied Physics,1991,30(9B):2339. |
[4] | 王悦辉,周济,崔学民,沈建红.低温共烧陶瓷(LTCC)技术在材料学上的进展[J].无机材料学报,2006(02):267-276. |
[5] | Kim D W;Lee D G;Hong K S .Low temperature firing and microwave dielectric properties of BaTi4O9 with Zn-B-O glass system[J].Materials Research Bulletin,2001,36:585. |
[6] | Yoon Ki Hyun;Park Moon Soo et al.Effect of B2O3-Li2O on microwave dielectric properties of(Ca0.275-Sm0.4 Li0.25)TiO3 ceramics[J].Journal of the European Ceramic Society,2003,23(14):2423. |
[7] | Choi S;Kimd W;Kim J R et al.Low-temperature sintering and microwave dielectric properties of BaO@(Nd1-xBix)2O3@4TiO2 by the glass additions[J].Ceramics International,2004,30:1181. |
[8] | 张启龙,杨辉,魏文霖,邹佳丽,尤源.烧结助剂对BiNbO4陶瓷烧结特性及介电性能的影响[J].电子元件与材料,2004(02):7-9. |
[9] | 陈尚坤,杨辉,王家邦,张启龙.BNT陶瓷低温烧成与性能[J].电子元件与材料,2004(05):3-5,11. |
[10] | 陈尚坤,杨辉,王家邦,张启龙.Ba4(Nd0.85Bi0.15)28/3Ti18O54陶瓷低温化研究[J].材料科学与工程学报,2005(01):84-87. |
[11] | 童建喜 .中介电常数低温共烧微波介质陶瓷及其器件研究[D].浙江大学,2006. |
[12] | Tong J X;Zhang Q L et al.Low-temperature firing and microwave dielectric properties of Ca[(Li0.33 Nb0.67)0.9 Ti0.1]-O3-δ ceramics with LiF addition[J].Materials Letters,2005,59:3252. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%