在BaO-Cr2O3-Nb2Os三元系统中,用固相反应法首次合成了新铌酸盐Ba6CrNb9O30.X射线衍射分析与介电特性测试结果表明,在室温下Ba6CrNb9O30属于填满型四方钨青铜结构,晶胞参数为:a=1.25691(3)nm,c=0.39755(3)nm,α=β=γ=90°;Ba6CrNb9O30在165℃从铁电相转变为顺电相.
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