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铜离子掺杂能够改变TiO2的光生载流子传输,从而影响光生电子-空穴的复合,因此铜离子掺杂能够提高TiO2的光催化活性.铜掺杂纳米TiO2在制备过程中容易受到制备技术、热处理温度等的影响,而使纳米TiO2的晶体结构和表面性质发生变化,这些变化主要体现在晶相结构变化、量子产率增加等方面.针对近年来铜掺杂TiO2的研究及应用进展,综述了影响其光催化效果的因素,指出晶相结构、制备方法、掺杂浓度、反应体系的pH值是主要因素,并提出了未来需要加强研究的方向.

参考文献

[1] Gao F;Liu X Y;Zheng L Y et al.Microstructure and properties of TiO2 thin films doped with Ni[J].Advances in Materials Research,2012,490-495:3306.
[2] Bao Y W;Tian L;Gong J H .Sol-gel preparation,characterization and photocatalytic activity of Co doped nano-TiO2[J].Advances in Materials Research,2010,177:54.
[3] Saehana S;Prasetyowati R;Hidayat M I et al.Efficiency improvement in TiC2-particle based solar cells after deposition of metal in spaces between particles[J].Int J Basic Appl Sci,2011,12:15.
[4] Jeon M K;Park J W;Kang M .Hydrogen production from methanol/water decomposition in a liquid photosystem using the anatase and rutile forms of Cu-TiO2[J].Journal of Industrial and Engineering Chemistry,2007,13(01):84.
[5] Wang J;Li R H;Zhang L Q et al.Sol-gel praparation of Fe-doped crystal TiO2 powder and its photocatalytic activity for degradation of azo fuchsine under visible light irradiation[J].Russian Journal of Inorganic Chemistry,2010,55(05):692.
[6] Gole JL;Prokes SM;Glembocki OJ .Efficient room-temperature conversion of anatase to rutile TiO2 induced by high-spin ion doping[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(6):1782-1788.
[7] Wang H X;Li G I;Kamiyama H .Pyrogenic iron(Ⅲ)-doped TiO2 nanopowders synthesized in RF thermal plasma:Phase formation,defect structure,band gap and magnetic properties[J].Journal of the American Chemical Society,2005,127:10982.
[8] Song S;Jun B;Chen G et al.Photocatalytic degradation of gaseous o-xylene over M-TiO2 (M =Ag,Fe,Cu,Co) in different humidity levels under visible-light irradiation:Activity and kinetic study[J].Rare Metals,2011,30(z1):147.
[9] ZHANG YunSong,WANG RenGuo,WANG XianXiang,LEI SanZhong,TONG DongMei.The comparison of Cu(Ⅱ) adsorption capability of baker's yeast, nano-titania and their composite adsorbent[J].科学通报(英文版),2008(09):1365-1372.
[10] WANG Biao,ZHAO YuDong,HU LiMing,CAO JunSheng,GAO FengLi,LIU Yun,WANG LiJun.Improved and excellent CO sensing properties of Cu-doped TiO2 nanofibers[J].科学通报(英文版),2010(03):228-232.
[11] 高飞,吴再华,刘晓艳.掺铜TiO2薄膜的制备及结构与光学性能的研究[J].半导体光电,2009(01):87-89,98.
[12] 唐丽娜,柳丽芬,董晓艳,杨凤林.金属掺杂二氧化钛光催化还原硝酸氮[J].环境科学,2008(09):2536-2541.
[13] You, M;Kim, TG;Sung, YM .Synthesis of Cu-Doped TiO2 Nanorods with Various Aspect Ratios and Dopant Concentrations[J].Crystal growth & design,2010(2):983-987.
[14] Slamet;Nasution H W;Purnama E et al.Effect of copper species in a photocatalytic synthesis of methanol from carbon dioxide over copper doped titania catalysts[J].World Appl Sci J,2009,6(01):112.
[15] Chen R F;Zhang C X;Deng J et al.Preparation and photocatalytic activity of Cu2+-doped TiO2/SiO2[J].Int J Miner,2009,16(02):220.
[16] 蔡国发 .纳米二氧化钛光催化剂的制备、表征、光催化性能及失活研究[D].武汉理工大学,2011.
[17] Wu J C S;Lin H M .Photo reduction of CO2 to methanol via TiO2 photocatalyst[J].International Journal of Photoenergy,2005,7:115.
[18] 次立杰,张绍岩,梁慧霞,常永芳,刘显龙.Cu/TiO2 纳米线的制备及其光催化性能[J].材料导报,2010(14):92-94.
[19] 凌洁.掺杂Cu2+纳米管和纳米粉体的制备及其性能对比[J].广东化工,2011(06):81-82.
[20] 王婷,郭丽,贺晓莹.掺杂改性纳米TiO2光催化剂的制备及表征[J].辽宁化工,2010(02):131-133.
[21] 杨雁南,张云怀,肖鹏,张小宁.纳米金属/TiO2复合材料的制备及应用研究[J].材料导报,2009(z2):157-160.
[22] Huo Y N;Yang X L;Zhu J et al.Highly active and stable Cds-TiO2 visible photocatalyst prepared by in situ sulfurization under supercritical conditions[J].Applied Catalysis B:Environmental,2011,106(1-2):69.
[23] Colon G;Maicu M;Hidalgo MC;Navio JA .Cu-doped TiO2 systems with improved photocatalytic activity[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2006(1/2):41-51.
[24] Li GT;Qu JH;Zhang XW;Liu HJ;Liu HN .Electrochemically assisted photocatalytic degradation of Orange II: Influence of initial pH values[J].Journal of molecular catalysis, A. Chemical,2006(1/2):238-244.
[25] Wang B;Yan J;Du S G et al.Study on the characterisation and photocatalysis reactivity of TiO2/Cu composite particles[J].Advances in Materials Research,2011,194-196:1480.
[26] 叶金花 .掺杂改性TiO<,2>的光催化性能及其灭菌性能研究[D].福建师范大学,2007.
[27] 胡庆华,张蔚萍,陈浩,王建国.Cu2+/TiO2纳米纤维掺杂比对一氯甲烷光催化降解的影响[J].无机盐工业,2010(11):23-25.
[28] 张浩,赵江平,王智懿.Cu-TiO2光催化降解甲醛气体的研究及应用[J].新型建筑材料,2009(09):78-81.
[29] 朱鹏飞,刘梅,李黎明,宋诚.铜铁双金属掺杂TiO2/膨润土光催化降解直接天蓝染料性能研究[J].非金属矿,2012(01):55-57,60.
[30] Granados O G;Ortega F M;Ferronato E P M C et al.Photoactivity of metal-phenylporphyrins adsorbed on TiO2 under visible light radiation:Influence of central metal[J].Open Mater Sci J,2010,4:15.
[31] 林雨露.掺铜TiO2光催化降解活性艳红X-3B的研究[J].江汉大学学报(自然科学版),2009(01):37-40.
[32] 薛向欣,纪伟,毛竹,阮伟东,赵冰,MA Stephen,LOMBARDI John R.Cu掺杂TiO2作为SERS基底的研究[J].中国科学(化学),2011(02):398-402.
[33] 晃闻柳;万勇;王云霞 等.Cu掺TiO2薄膜的摩擦学性能[J].物理化学学报,2010,26(08):2317.
[34] Akbar Eshaghi;Ameneh Eshaghi .Fabrication of Copper Loaded Titania Nanostructure Thin Film and Studies the Optical and Hydrophilic Properties[J].Current Nanoscience,2012(3):323-327.
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