太阳电池单晶Si片表面制绒已是一项成熟的工艺,但普遍制绒时间较长.为提高制绒效率,本课题研究了较短时间内NaOH/ 异丙醇(IPA)体系制绒时的温度、时间、溶液组分对绒面的影响,以及制绒前去损伤的优劣.最终实现了,在含2.5%NaOH(质量百分比,下同)和10%IPA的溶液中,80℃恒温处理15 min即可制备出比较均匀的绒面.溶液中加入3%Na2SiO3,效果更佳,反射率最低可达9.5%.并发现去损伤后制绒效果并不理想,同时还研究了表面活性剂1,4-环己二醇(CHX)和十二烷基苯磺酸钠(SDBS)代替异丙醇制绒.研究发现,异内醇仍然是性价比较好的添加剂.
参考文献
[1] | 孟庆蕾,李方馨,席曦,钱维莹,阙立志,季静佳,丁玉强,李果华.PEDOT:PSS/ZnPc作为有机小分子太阳电池阳极修饰层的研究[J].人工晶体学报,2010(03):670-674. |
[2] | 李海玲,赵雷,刁宏伟,周春兰,王文静.单晶硅制绒中影响金字塔结构因素的分析[J].人工晶体学报,2010(04):857-861. |
[3] | Manea E;Budianu E;Purica M;Cristea D;Cernica I;Muller R;Poladian VM .Optimization of front surface texturing processes for high-efficiency silicon solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2005(1/4):423-431. |
[4] | 席珍强,杨德仁,吴丹,张辉,陈君,李先杭,黄笑容,蒋敏,阙端麟.单晶硅太阳电池的表面织构化[J].太阳能学报,2002(03):285-289. |
[5] | 谢建,马勇刚,廖华,苏庆益,李景天,杨丽娟.太阳电池及其应用技术讲座(三)各种太阳电池[J].可再生能源,2007(03):108-112. |
[6] | Muoza D;Carreras P;Escarré J et al.Optimization of KOH Etching Process to Obtain Textured Substrates Suitable for Heterojuncfion Solar Cells Fabricated by HWCVD[J].THIN SOLID FILMS,2009,517:3578-3580. |
[7] | 王涓,孙岳明,黄庆安,周再发.单晶硅各向异性湿法腐蚀机理的研究进展[J].化工时刊,2004(06):1-4,24. |
[8] | Seidel H;Csepregi L .Anisotropic Etching of Crystalline Silicon in Alkaline Solutions Ⅰ.Orientation Dependence and Behavior of Pssivation Layers[J].Journal of the Electrochemical Society,1990,137(11):3626-3632. |
[9] | Moldovan C;Insub R;Dascalu D et al.Anisotropic Etching of Silicon in a Complexant Redox Alkaline System[J].Sensors and Actuators B: Chemical,1999,58:438-449. |
[10] | 王淑珍,乔琦,陈肖静,王永谦,朱拓,张光春,施正荣,李果华.制绒Si片清洗工艺的研究[J].半导体技术,2010(04):305-308. |
[11] | 邓淑芳,白敏冬,白希尧,刘兴旺.羟基自由基特性及其化学反应[J].大连海事大学学报,2004(03):62-64. |
[12] | Kim JM;Kim YK .The enhancement of homogeneity in the textured structure of silicon crystal by using ultrasonic wave in the caustic etching process[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2004(2):239-247. |
[13] | Singh PK.;Lal M.;Singh SN.;Das BK.;Kumar R. .Effectiveness of anisotropic etching of silicon in aqueous alkaline solutions[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(1):103-113. |
[14] | Fornies E;Zaldo C;Albella JM .Control of random texture of monocrystalline silicon cells by angle-resolved optical reflectance[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2005(1/4):583-593. |
[15] | 杨志平,杨勇,励旭东,许颖,王文静.硅酸钠在太阳能电池单晶硅表面织构化的作用[J].硅酸盐学报,2005(12):1472-1476. |
[16] | Birmann K;Zimmer M;Rentsch J.Fast Alkaline Etching of Monocrystalline Wafers in KOH/CHX[A].Valencia,Spain,2008:1-5. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%