综述了中低温下高电导率CeO2基电解质材料研究的最新进展,重点评述了双掺杂和纳米复相提升CeQ基电解质材料电导率和抑制电子电导的机理,并指出了未来CeO2基电解质材料的发展方向.
参考文献
[1] | Shao, ZP;Haile, SM .A high-performance cathode for the next generation of solid-oxide fuel cells[J].Nature,2004(7005):170-173. |
[2] | Liu, Y;Zha, SW;Liu, ML .Nanocomposite electrodes fabricated by a particle-solution spraying process for low-temperature SOFCs[J].Chemistry of Materials,2004(18):3502-3506. |
[3] | Abrantes J C C;Pérez-Coll D;Nú(n)ez P et al.Electronic transport in Ce0.8 Smm0.2O1.9-δ ceramics under reducing conditions[J].Electrochimica Acta,2003,48(19):2761. |
[4] | Jianbing Huang;Fucheng Xie;Cheng Wang;Zongqiang Mao .Development of solid oxide fuel cell materials for intermediate-to-low temperature operation[J].International journal of hydrogen energy,2012(1):877-883. |
[5] | Yen-Pei Fu .Microwave-induced combustion synthesis and ionic conductivity of Ce_(0.8)(Gd_(0.2-x)Sm_x)O_(1.90) ceramics[J].CERAMICS INTERNATIONAL,2008(8):2051-2057. |
[6] | Ramesh S;Kumar V P;Kistaiah P et al.Preparation,characterization and thermo electrical properties of co-doped Ce0.8 x Sm0.2 CaxO2-δ materials[J].Solid State Ionics,2010,181(1-2):86. |
[7] | Parkash, O.;Singh, N.;Singh, N.K.;Kumar, D..Preparation and characterization of ceria co-doped with Ca and Mg[J].Solid state ionics,2012:100-105. |
[8] | Huang HB;Mao ZQ;Liu ZX;Wang C .Development of novel low-temperature SOFCs with co-ionic conducting SDC-carbonate composite electrolytes[J].Electrochemistry communications,2007(10):2601-2605. |
[9] | Samarium doped ceria-(Li/Na)_2CO_3 composite electrolyte and its electrochemical properties in low temperature solid oxide fuel cell[J].Journal of Power Sources,2010(15):p.4695. |
[10] | Lei Zhang;Rong Lan;Xiaoxiang Xu;Shanwen Tao;Yinzhu Jiang;Arno Kraft .A high performance intermediate temperature fuel cell based on a thick oxide-carbonate electrolyte[J].Journal of Power Sources,2009(2):588-600. |
[11] | Maricle D L;Swarr T E;Karavolis S .Enhanced ceria-A low-temperature SOFC electrolyte[J].Solid State Ionics,1992,52(1-3):173. |
[12] | van Herle J;Seneviratne D;Mcevoy A J .Lanthanide co-doping of solid electrolytes:AC conductivity behaviour[J].Journal of the European Ceramic Society,1999,19(6-7):837. |
[13] | Study on calcium and samarium co-doped ceria based nanocomposite electrolytes[J].Journal of Power Sources,2010(19):P.6491. |
[14] | Dikmen S .Effect of co-doping with Sm3+,Bi3-,La3+,and Nd3+ on the electrochemical properties of hydrothermally prepared gadolinium-doped ceria ceramics[J].Journal of Alloys and Compounds,2010,491(1-2):106. |
[15] | Yifeng Zheng;Haitao Gu;Han Chen;Ling Gao;Xiaofang Zhu;Lucun Guo .Effect Of Sm And Mg Co-doping On The Properties Of Ceria-based Electrolyte Materials For It-sofcs[J].Materials Research Bulletin,2009(4):775-779. |
[16] | Inaba H.;Tagawa H. .CERIA-BASED SOLID ELECTROLYTES - REVIEW [Review][J].Solid state ionics,1996(1/2):1-16. |
[17] | Y. Ji;J. Liu;T. He .The effect of Pr co-dopant on the performance of solid oxide fuel cells with Sm-doped ceria electrolyte[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2005(1/2):317-322. |
[18] | Kim D J .Lattice parameters,ionic conductivities,and solubility limits in fluorite-structure MO2 oxide[M =HP+,Zr4+,Ce4+,Th4+,U4+]solid solutions[J].Journal of the American Ceramic Society,1989,72(08):1415. |
[19] | Steele BCH.;Uchino S.;Hori KM. .Kinetic parameters influencing the performance of IT-SOFC composite electrodes[J].Solid state ionics,2000(1/4):445-450. |
[20] | Banerjee S;Devi PS;Topwal D;Mandal S;Menon K .Enhanced ionic conductivity in Ce0.8Sm0.2O1.9: Unique effect of calcium co-doping[J].Advanced functional materials,2007(15):2847-2854. |
[21] | 杨建平,陈志刚,李霞章,陈杨.CeO2基中温电解质材料的掺杂改性[J].电源技术,2006(08):684-688. |
[22] | 梁广川,刘文西,陈玉如,杜春生.Sm,Gd共同掺杂的CeO2基电解质性能研究[J].硅酸盐学报,2000(01):44-46. |
[23] | Vanherle J.;Kawada T.;Sakai N.;Yokokawa H.;Dokiya M.;Horita T. .LOW TEMPERATURE FABRICATION OF (Y,GD,SM)-DOPED CERIA ELECTROLYTE[J].Solid state ionics,1996(2):1255-1258. |
[24] | Yingchao Dong;Stuart Hampshire;Jian-er Zhou .Combustion synthesis and characterization of Cu-Sm co-doped CeO_2 electrolytes[J].Journal of the European Ceramic Society,2011(13):2365-2376. |
[25] | Xiangfeng Guan;Heping Zhou;Zhihui Liu;Yanan Wang;Jun Zhang .High performance Gd~(3+) and Y~(3+) co-doped ceria-based electrolytes for intermediate temperature solid oxide fuel cells[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2008(4):1046-1054. |
[26] | Guan X;Zhou H;Wang Y et al.Preparation and properties of Gd3+ and y3+ co-doped ceria-based electrolytes for intermediate temperature solid oxide fuel cells[J].Journal of Alloys and Compounds,2008,464(1-2):310. |
[27] | Prashanth Kumar V;Reddy Y S;Kistaiah P et al.Thermal and electrical properties of rare-earth co-doped ceria ceramics[J].Materials Chemistry and Physics,2008,112(02):711. |
[28] | Magdalena Dudek .Ceramic oxide electrolytes based on CeO_2--Preparation, properties and possibility of application to electrochemical devices[J].Journal of the European Ceramic Society,2008(5):965-971. |
[29] | Liang C C .Conduction characteristics of the lithium iodidealuminum oxide solid electrolytes[J].Journal of the Electrochemical Society,1973,120(07):1289. |
[30] | Zhu B;Li S;Mellander BE .Theoretical approach on ceria-based two-phase electrolytes for low temperature (300-600 degrees C) solid oxide fuel cells[J].Electrochemistry communications,2008(2):302-305. |
[31] | Raza R;Qin H;Fan L et al.Electrochemical study on codoped ceria-carbonate composite electrolyte[J].Journal of Power Sources,2012,201(0):121. |
[32] | Wang XD;Ma Y;Raza R;Muhammed M;Zhu B .Novel core-shell SDC/amorphous Na2CO3 nanocomposite electrolyte for low-temperature SOFCs[J].Electrochemistry communications,2008(10):1617-1620. |
[33] | Gao Z;Raza R;Zhu B et al.Preparation and characterization of Srn0.2 Ce0.8 O1.9/Na2 CO3 nanocomposite electrolyte for low-temperature solid oxide fuel cells[J].International Journal of Hydrogen Energy,2011,36(06):3984. |
[34] | Improved ceria-carbonate composite electrolytes[J].International journal of hydrogen energy,2010(7):2684. |
[35] | Zhang, L.;Lan, R.;Kraft, A.;Tao, S. .A stable intermediate temperature fuel cell based on doped-ceria-carbonate composite electrolyte and perovskite cathode[J].Electrochemistry communications,2011(6):582-585. |
[36] | 高冬云,郭瑞松.Yb掺杂锆酸钡/硫酸盐复相质子导体的研究[J].稀有金属材料与工程,2009(z2):696-699. |
[37] | 彭珍珍,郭瑞松,尹自光,李娟,蔡舒.BaZrO3/NaOH复相质子导体的制备与性能[J].稀有金属材料与工程,2007(z2):596-598. |
[38] | Raza, R.;Abbas, G.;Wang, X.;Ma, Y.;Zhu, B. .Electrochemical study of the composite electrolyte based on samaria-doped ceria and containing yttria as a second phase[J].Solid state ionics,2011(1):58-63. |
[39] | Effects of salt composition on the electrical properties of samaria-doped ceria/carbonate composite electrolytes for low-temperature SOFCs[J].International journal of hydrogen energy,2010(9):4270. |
[40] | Xiaodi Wang;Ying Ma;Shanghua Li;Bin Zhu;Mamoun Muhammed .SDC/Na_2CO_3 nanocomposite: New freeze drying based synthesis and application as electrolyte in low-temperature solid oxide fuel cells[J].International journal of hydrogen energy,2012(24):19380-19387. |
[41] | Yimg Ma;Xiaodi Wang;Shanghua Li;Muhammet S. Toprak;Bin Zhu;Mamoun Muhammed .Samarium-Doped Ceria Nanowires: Novel Synthesis and Application in Low-Temperature Solid Oxide Fuel Cells[J].Advanced Materials,2010(14):1640-1644. |
[42] | 贾慧娴,黄建兵,张萍,高展,毛宗强,史玉芳.低温固体氧化物燃料电池SDC-(Li/Na)2CO3复合电解质材料优化[J].太阳能学报,2009(07):979-984. |
[43] | SDC-LiNa carbonate composite and nanocomposite electrolytes[J].International journal of hydrogen energy,2010(7):2970. |
[44] | 朱晓东,孙克宁,周德瑞.稳定的ZrO2基SOFC中CeO2夹层的制备方法和作用机制[J].化学进展,2007(11):1710-1717. |
[45] | Tsai T;Perry E;Barnett S .Low-temperature solid-oxide fuel cells (SOFC's) utilizing thin bilayer electrolytes[J].Journal of the Electrochemical Society,1997,144(05):L130. |
[46] | Mogens M .Physical properties of mixed conductor solid oxide fuel anodes of doped CeO2[J].Journal of the Electrochemical Society,1994,141(08):2122. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%