综述了聚合物力化学的基本理论研究和在聚合物合成方面的应用研究,阐述了聚合物在力场作用下的降解及聚合机理,介绍了力化学方法进行聚合物合成和改性的特点及优势。
In this paper, the research on basic theory and application of mechanochemistry in polymeric synthesis were reviewed. Mechanism of mechanochemical degradation and synthesis was introduced. Polymeric chain scission take place nonrandomly and randomly and macroinitiators are obtained under stress field due to shear deformation, ultrason and high pressure, etc. The macroinitiators are able to initiate active monomers and obtain block or／and graft copolymers in polymer-monomer system. Block or／and graft copolymers were obtained in polymer-polymer system. The special properties and advantages of mechanochemistry were also presented.
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