电解法制备了Ag/AgCl参比电极，并用电子探针分析了其形貌及成分，跟踪了电极在3.5％NaCl溶液中的电位稳定性及长期极差变化，研究了电极对Cl－和温度的响应，并采用恒电流极化的方式测量了其抗极化性能。结果表明，所制备的Ag/AgCl参比电极在3.5％NaCl中稳定性、准确性良好，长期极差变化小，对Cl－响应性好，温度系数小，不易极化，可尝试作为高精度测量装置的敏感元件使用。
A silver-silver chloride reference probe has been made by electrolytic method and its structure and ingredient is characterized with EPMA. A series of its performances are studied. The results show that the silver-silver chloride reference probe has good properties such as stability and precision in 3.5%NaCl, the little potential difference between two probes in long term, the response property to temperature and the concentration of Cl－, antipolarization. Thus the probe studied probably can be used as sense organ in the precision instrument of electrochemical measurement.
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