材料期刊网

By using strong-field scheme, the complete d(5) energy matrix with D-2d symmetry has been constructed. Then, by diagonalization of this matrix at normal and various pressures, the whole energy spectrum [including the ground-state zero-field splitting (GSZFS)] and its pressure-induced shift (PS) of ZnTe:Mn2+ have uniformly been calculated. The results are in very good agreement with experimental data. According to the eigenfunctions and PS, the assignments of four absorption bands have been given. By taking into account the effect of different deformations of t(2) and e radial wavefunctions on t(2)(3)((4)A(2))e(2)((3)A(2))(4)A(1) and t(2)(3)(E-2)e(2)((3)A(2))E-4, the position of the third absorption band at normal pressure has been estimated. The tetragonal field is important for GSZFS of ZnTe:Mn2+ and its PS, which supports the existence of tetragonal Jahn-Teller distortion in ZnTe:Mn2+. The physical essentials of typical levels, GSZFS and their PS have been revealed.