简要介绍了高压合成法、固态反应法、水热/溶剂热法、机械合金化法、磁电溅射法、低温回流法等几种制备Co基过渡金属硫族化合物的方法,综述了质子交换膜燃料电池(PEMFC)阴极Co基过渡金属硫族化合物催化剂的研究进展,重点讨论了Co-Se、Co-S、Co-Te等催化剂对氧还原反应(ORR)的催化活性,提出了阴极Co基过渡金属硫族化合物催化剂存在的问题以及发展趋势.
参考文献
| [1] | Oszcipok M;Zedda M;Hesselmann J et al.Portable proton exchange membrane fuel-cell systems for outdoor applications[J].Journal of Power Sources,2006,157:666. |
| [2] | C. Cremers;M. Scholz;W. Seliger;A. Racz;W. Knechtel;J. Rittmayr;F. Grafwallner;H. Peller;U. Stimming .Developments for Improved Direct Methanol Fuel Cell Stacks for Portable Power[J].Fuel cells,2007(1):21-31. |
| [3] | Cheng H;Yuan W;Scott K .A liquid-gas phase mixedreactant fuel cell with a RuSeW cathode electrocatalyst[J].Journal of Power Sources,2008,183:678. |
| [4] | Ezeta A;Arce E M;Solorza O et al.Effect of the leaching of Ru-Se-Fe and Ru-Mo-Fe obtained by mechanical alloying on electrocatalytical behavior for the oxygen reduction reaction[J].Journal of Alloys and Compounds,2009,483:429. |
| [5] | Lefevre M;Dodelet J P;Bertrand P .Molecular oxygen reduction in PEM fuel cell conditions:ToF-SIMS analysis of Co-based electrocatalysts[J].Journal of Physical Chemistry B,2005,109:16718. |
| [6] | 李赏,周彦方,邱鹏,潘牧.Co基非贵金属催化剂的制备及其氧还原电催化性能[J].科学通报,2009(07):881-887. |
| [7] | Xia D;Liu S;Wang Z et al.Methanol-tolerant MoN electrocatalyst synthesized through heat treatment of molybdenum tetraphenylporphyrin for four-electron oxygen reduction reaction[J].Journal of Power Sources,2008,177:296. |
| [8] | Liu LY;Kim H;Lee JW;Popov BN .Development of ruthenium-based catalysts for oxygen reduction reaction[J].Journal of the Electrochemical Society,2007(2):A123-A128. |
| [9] | Lei Zhang;Kunchan Lee;Jiujun Zhang .The effect of heat treatment on nanoparticle size and ORR activity for carbon-supported Pd-Co alloy electrocatalysts[J].Electrochimica Acta,2007(9):3088-3094. |
| [10] | Lin, CL;Sanchez-Sanchez, CM;Bard, AJ .Methanol tolerance of Pd-Co oxygen reduction reaction electrocatalysts using scanning electrochemical microscopy[J].Electrochemical and solid-state letters,2008(8):B136-B139. |
| [11] | Bither T A;Bouchard R J;Cloud W H et al.Transition metal pyrite dichalcogenides-high pressure synthesis and correlation of properties[J].Inorganic Chemistry,1968,7(11):2208. |
| [12] | Sleight A W;Bither T A .New chromium chalcogenideaprepared at high pressure and the crystal growth of chromiurn sesquisufide[J].Inorganic Chemistry,1969,8(03):566. |
| [13] | Goto T.;Takahashi H.;Ogawa S.;Shindo Y. .MAGNETIC PROPERTIES OF THE ITINERANT METAMAGNETIC SYSTEM CO(S1-XSEX)(2) UNDER HIGH MAGNETIC FIELDS AND HIGH PRESSURE[J].Physical Review.B.Condensed Matter,1997(21):14019-14028. |
| [14] | 杨金虎,王杭栋,杜建华,张瞩君,方明虎.Co（S1-xSex）2系统中的铁磁量子相变[J].物理学报,2009(02):1195-1199. |
| [15] | Javier F G G;Larsson A K;Norèn L.The crystal structures of Co3Se4 and Co7Se8[J].Solid State Sciences,2004(06):725. |
| [16] | Pocha R;Lohnert C;Johrendt D .The metal-rich palladium chalcogenides Pd2 MX2(M = Fe、Co、Ni;X = Se、Te):Crystal structure and topology of the electron density[J].Journal of Solid State Chemistry,2007,180:191. |
| [17] | Zhang WX.;Liu JW.;Hui ZH.;Yu WC.;Qian YT.;Zhou GE.;Yang L.;Yang ZH. .A hydrothermal synthesis of orthorhombic nanocrystalline cobalt diselenide CoSe2[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2000(14/15):2403-2408. |
| [18] | Han ZH.;Lu J.;Yu SH.;Zhao HQ.;Qian YT.;Li YP. .Preparation of late transition metal selenides with different morphologies in ethylenediamine[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2000(11):1825-1829. |
| [19] | Zhan JH.;Li SD.;Xie Y.;Yu WC.;Qian YT.;Yang XG. .Synthesis of nanocrystalline cobalt selenide in nonaqueous solvent[J].International Journal of Quantum Chemistry,2000(2):537-539. |
| [20] | Chen X;Fan R .Low-temperature hydrothermal synthesis of transition metal dichalcogenides[J].Chemistry of Materials,2001,13:802. |
| [21] | Lu Q;Hu J;Tang K et al.A simple synthetic method for MSe2(M= Fe,Co or Ni)nanocrystallites at low temperature[J].Materials Chemistry and Physics,2001,69:278. |
| [22] | Yang J;Chang G;Zeng J et al.Shape control and characterization of transition metal diselenides MSe2(M=Ni,Co,Fe)prepared by a solvothermal-reduction process[J].Chemistry of Materials,2001,13:848. |
| [23] | Campos C E M;Lima J C;Grandi T A et al.Structural studies of cobalt selenides prepared by mechanical alloying[J].Physica B,2002,324:409. |
| [24] | Campos C E M;Lima J C;Grandi T A et al.Hexagonal COSe formation in mechanical alloyed Co75Se25 mixture[J].Solid State Communications,2004,131:265. |
| [25] | Susac D;Sode A;Zhu L;Wong PC;Teo M;Bizzotto D;Mitchell KAR;Parsons RR;Campbell SA .A methodology for investigating new nonprecious metal catalysts for PEM fuel cells[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(22):10762-10770. |
| [26] | Vayner E;Sidik R A;Anderson A B et al.Experimental and theoretical study of cobalt selenide as a catalyst for O2[J].Journal of Physical Chemistry,2006,111:10508. |
| [27] | Teo M;Wong PC;Zhu L;Susac D;Campbell SA;Mitchell KAR;Parsons RR;Bizzotto D .Characterization of a Co-Se thin film by scanning Auger microscopy and Raman spectroscopy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(3):1130-1134. |
| [28] | Zhu L;Susac D;Lam A;Teo M;Wong PC;Bizzotto D;Campbell SA;Parsons RR;Mitchell KAR .Structure of sputtered Co-Se thin films prepared for an application in catalysis[J].International Journal of Quantum Chemistry,2006(12):3942-3948. |
| [29] | Feng Y;He T;Alonso-Vante N .In situ free-surfactant synthesis and ORR electrochemistry of carbon-supported Co3S4 and CoSe2 nanoparticles[J].Chemistry of Materials,2008,20:26. |
| [30] | Feng Y;He T;Alonso-Vante N .Oxygen reduction reaction on carbon-supported CoSe2 nanoparticles in an acidic medium[J].Electrochimica Acta,2009,54:5252. |
| [31] | Feng Y;He T;Alonso-Vante N .Carbon-supported CoSe2 nanoparticles for oxygen reduction reaction in acid medium[J].Fuel Cells,2009,9:1. |
| [32] | Lee K;Zhang L;Zhang JJ .Ternary non-noble metal chalcogenide (W-Co-Se) as electrocatalyst for oxygen reduction reaction[J].Electrochemistry communications,2007(7):1704-1708. |
| [33] | Behret H;Sandstede G .Electrocatalytic oxygen reduction with thiospinels and other sulphides of transition metals[J].Electrochimica Acta,1975,20(02):111. |
| [34] | Sidik R A;Anderson A B .Co9S8 as a catalyst for electroreduction of O2:Quantum chemistry predictions[J].Journal of Physical Chemistry,2006,110:936. |
| [35] | Susac D;Zhu L;Teo M et al.Characterization of FeS2based thin film as model catalysts for the oxygen reduction reaction[J].Physical Chemistry,2007,111:18715. |
| [36] | Qiu G;Xiao Q;Hu Y et al.Theoretical study of the surface energy and electronic structure of pyrite FeS2(100)using a total-energy pseudopotential method,CASTEP[J].Journal of Colloid and Interface Science,2004,270:127. |
| [37] | Zhu L;Susac D;Tea M;Wong KC;Wong PC;Parsons RR;Bizzotto D;Mitchell KAR;Campbell SA .Investigation of CoS2-based thin films as model catalysts for the oxygen reduction reaction[J].Journal of Catalysis,2008(1):235-242. |
| [38] | Hara Y;Minami N;Itagaki H .Electrocatalytic properties of ruthenium modified with Te metal for the oxygen reduction reaction[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2008(1):59-66. |
| [39] | Wu G;Cui G;Li D et al.Carbon-supported Co1.67Te2 nanoparticles as electrocatalysts for oxygen reduction reaction in alkaline electrolyte[J].Journal of Materials Chemistry,2009,19:6581. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%