以马来酸酐接枝乙烯-辛烯共聚物(POE-g-MAH)作为增容剂,采用熔体共混的方法制备了PA1010-PP 共混物,通过扫描电镜(SEM)、力学性能和差示扫描量热(DSC)测试,研究了动态保压注射成型中POE-g-MAH对PA1010-PP共混物的增容作用.力学性能测试结果表明,在注射成型过程中施加剪切应力,明显提高了共混物的拉伸和冲击性能.SEM结果表明,剪切诱导制品产生多层次结构,而且分散相相区尺寸显著减小,分散更趋均匀,相界面更加模糊.DSC结果表明,剪切应力作用下,当POE-g-MAH的质量分数达到15%时,PP出现2个结晶峰,即出现异相成核结晶和均相成核结晶,PP均相成核结晶的出现从另一个方面表明动态试样中分散相PP尺寸小于静态试样.剪切应力作用下增容作用的提高归因于剪切应力作用下独特相形态的形成.
参考文献
[1] | 张明,张云灿,吕忆农.相容性对PA66/POE共混材料形态、微结构及力学性能的影响[J].复合材料学报,2005,22(5):113-119.Zhang Ming,Zhang Yuncan,Ln Yinong.Effects of miscibility on the morphology and microstructure and mechanical properties of PA66/POE blends[J].Acta Materiae Compositae Sinica,2005,22(5):113-119. |
[2] | 严伟,秦舒浩,于杰,等.有机蒙脱土对ABS-PA6共混物形态结构与力学性能的影响[J].复合材料学报,2010,27(1):37-41.Yan Wei,Qin Shuhao,Yu Jie,et al.Effects of organic montmorillonite on morphology and mechanical properties of acrylonitrile-butadiene-styrene(ABS)-polyamide 6(PA6)blends[J].Acta Materiae Compositae Siniea,2010,27(1):37-41. |
[3] | 王军祥,顾明元,朱真才,等.碳纤维和二硫化钼混杂增强尼龙复合材料的摩擦学性能研究[J].复合材料学报,2003,20(2):13-18.Wang Junxiang,Gu Mingyuan,Zhu Zhencai,et al.Tribological properties of hybrid carbon fiber and MoS2 reinforced polyamide 1010 composites[J].Acta Materiae Compositae Sinica,2003,20(2):13-18. |
[4] | Zhang Xiaomin,Yin Zhihui.Na Tainhai,et al.Morphology,mechanical properties and interaction behaviour of PA1010/PP/PP-g-GMA ternary blends[J].Polymer,1997,38(24):5905-5912. |
[5] | Yen Litang,Sheng Jing.Analysis of phase morphology and dynamics of immiscible PP/PA1010 blends and its partial-miscible blends during melt mixing from SEM pattern[J].Polymer,2006,47(8):2894-2903. |
[6] | Zhang Xiaomin,Yin Jinghua.Interaction characterization of PA1010/PP blends using PP-g-AA as compatibilizer[J].Polymer Engineering and Science,1997,37(1):197-204. |
[7] | 杨风霞,杜荣昵,李博,等.POE-g-MAH反应性增容PA1010/PP共混物的性能研究[J].高分子学报,2010(3):366-371.Yang Fengxia,Du Rongni,Li Bo,et al.Properties of PA1010/PPblends modified by reactive compatibilization with POE-g-MAH[J].Acta Polymer Sinics,2010(3):366-371. |
[8] | Kusmono,Mohd Ishak Z A,Chow W S,et al.Compatibilizing effect of SEBS-g-MA on the mechanical properties of different types of OMMT filled polyamide 6/polypropylene nanocomposites[J].Composites Part A.2008,39(12):1802-1814. |
[9] | Wang Cong,Su Juanxia,Li Jiang,et al.Phase morphology and toughing mechanism of polyamide 6/EPDM-g-MA blends obtained via dynamic packing injection molding[J].Polymer,2006,47(9):3197-3206. |
[10] | Wang Yong,Xiao Yan,Zhang Qin,et al.The morphology and mechanical properties of dynamic packing injection molded PP/PS blends[J].Polymer,2003,44(5):1469-1480. |
[11] | Li Jiang,Zhang Qin,Wang Cong,et al.Effect of compatibility on phase morphology and orientation of isotactic polypropylene(IPP)blends obtained by dynamic packing injection molding[J].Chinese Journal of Polymer Science,2006,24(4):379-387. |
[12] | 傅强.聚烯烃注射成型[M].北京:科学出版社,2007:2-4. |
[13] | 杨风霞,杜荣昵,罗锋,等.PTW对PA1010/PP共混物的增容作用[J].高等学校化学学报,2010,31(1):186-192.Yang Fengxia,Du Rongni,Luo Feng,et al.Compatibilization effect of PTW on polymer blends of PA1010/PP[J].Chemical Journal of Chinese Universities,2010,31(1):186-192. |
[14] | 陈广新,刘景江.尼龙1010分别与未接枝和接枝马来酸酐的高抗冲聚苯乙烯的共混体系研究[J].高分子学报,1999(5):557-563.Chen Guangxin,Liu Jingjiang.Blends of polyamide 1010 with ungrafted and maleie anhydride grafted high impact polystyrene[J].Acta Polymer Sinica,1999(5):557-563. |
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