采用Er3Ni吸氢反应装置对样品进行充分活化后,分析粒度、反应温度和反应平衡压力对Er3Ni氢化反应的孕育时间和吸氢量的影响,分析同反应条件下Er3Ni的氢化反应过程及产物特性,为探索其作为低温制冷机新型回热材料的可行性创造条件.
In order to better understand the mechanism of the reaction characteristics of Er3Ni hydrogenation, a self-built hydrogen-adsorption experimental apparatus was used to study the effects of particle size, reaction temperature and pressure on the induction time of Er3Ni hydrogenation reaction and the hydrogen adsorption capacity, based on which the hydrogenation characteristics of Er3Ni were then discussed. The results show mat activation has a great effect on hydrogen absorption capacity of Er3Ni. The influence of particle size of Er3Ni is mainly on the induction time. Lower reaction temperature needs longer induction time of accumulating energy to overcome the energy barrier of hydrogenation. The value x in Er3NiHx is insensitive to the reaction equilibrium pressure. Hydrides Er3NiHx reaches equilibrium at an extremely low pressure, about 10 kPa.
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