During the growth of the hot filament chemical vapor deposition(HFCVD)diamond films, numerical simulations in a 2-D mathematical model were employed to investigate the influence of various deposition parameters on the gas physical parameters, including the temperature, velocity and volume density of gas. It was found that, even in the case of optimized deposition parameters, the space distributions of gas parameters were heterogeneous due primarily to the thermal blockage come from the hot filaments and cryogenic pump effect arisen from the cold reactor wall. The distribution of volume density agreed well with the thermal round-flow phenomenon, one of the key obstacles to obtaining high growth rate in HFCVD process. In virtue of isothermal boundary with high temperature or adiabatic boundary condition of reactor wall, however, the thermal roundflow was profoundly reduced and as a consequence, the uniformity of gas physical parameters was considerably improved, as identified by the experimental films growth.
参考文献
[1] | S Matsumoto;Y Sato;M Kamo;N Setaka .[J].Japanese Journal of Applied Physics,1982,21:L183. |
[2] | J C Angus;C C Hayman .[J].Science,1988,241:913. |
[3] | W A Yarbrough;R Messier .[J].Science,1990,247:688. |
[4] | M Uede;Y Takagi .[J].Journal of Materials Research,2001,16:3069. |
[5] | E Kondoh;T Ohta;T Mitomo;K Ohtsuka .[J].Journal of Applied Physics,1992,72:705. |
[6] | G H Song;C Sun;B Wang;A Y Wang, R F Huang and L S Wen .[J].Materials Letters,2001,48(08) |
[7] | C Wolden;S Mitra;K K Gleason .[J].Journal of Applied Physics,1992,72:3750. |
[8] | G. H. Song;C. Sun;R. F. Huang;L. S. Wen;C. X. Shi .Heat transfer simulation of HFCVD and fundamentals of diamond vapor growth reactor designing[J].Surface & Coatings Technology,2000(1/3):500-505. |
[9] | A Y Wang;C Sun;R F Huang;L S Wen .[J].Journal of Materials Science and Technology,2003,19:22. |
[10] | M R Shen;H Wang;Z Y Ning;C Ye and Z X Ren.[J].Journal of Physics:Condensed Matter,1996(08):8953. |
[11] | M C Mcmaster;W L Hsu;M E Coltrin;D S Dandy .[J].Journal of Applied Physics,1994,76:7567. |
[12] | E J Corat;D G Goodwin .[J].Journal of Applied Physics,1993,74:2021. |
[13] | D S Dandy;M E Coltrin .[J].Journal of Applied Physics,1994,76:3102. |
[14] | Y A Mankelevich;N V Suetin;M N R Ashfold;J A Smith and E Cameron.[J].Diamond and Related Materials,2001(10):304. |
[15] | A Y Wang;C Sun;H T Cao;A L Ji, R F Huang and L S Wen.[J].Modelling and Simulation in Materials Science and Engineering,2004(12):325. |
[16] | 汪爱英,柯培玲,孙超,黄荣芳,闻立时.热丝CVD大面积金刚石薄膜的生长动力学研究[J].新型炭材料,2005(03):229-234. |
[17] | F Jansen;M A Machonkin;D E Kuhman.[J].Journal of Vacuum Science and Technology A-Vacuum Surfaces and Films,1990(08):3785. |
[18] | D G Goodwill;G G Gavillet .[J].Journal of Applied Physics,1990,68:6393. |
[19] | J Yu;R F Huang;L S Wen;C X Shi .[J].Journal of Materials Science Letters,1998,17:1011. |
[20] | G.H. Song;J.H. Yoon;H.S. Kim .Influence of hot filaments arranging on substrate temperature during HFCVD of diamond films[J].Materials Letters,2002(5):832-837. |
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