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采用金相显微镜、扫描电子显微镜和Х射线衍射仪显微分析技术,研究了强化固溶工艺对含Sr 2099(Al-2.52Cu-1.87Li-1.19Zn-0.497Mg-0.309Mn-0.0825Zr-0.0605Sr)型铝锂合金抗晶间腐蚀和抗剥落腐蚀性能的影响。结果表明:与常规固溶(540℃×2 h)+T8时效(121℃×14 h+151℃×48 h)工艺相比,强化固溶(540℃×2 h+550℃×2.67 h)+T8时效(121℃×14 h+151℃×48 h)工艺显著减少了合金中的粗大未溶相,再结晶程度提高,细化了晶粒,且促进等轴晶的形成。按晶间腐蚀标准(GB7998-2005)和剥落腐蚀标准(GB/T 22639-2008),强化固溶+T8时效工艺降低了该合金的抗晶间腐蚀能力,但显著提高了该合金的抗剥落腐蚀能力。

The effects of enhanced solid solution treatment on intergranular corrosion and exfoliation corrosion behavior of Sr microalloyed 2099 ( A1-2.52Cu-1.87Li-1.19Zn-0. 497Mg-0. 309Mn-0. 0825Zr-0. 0605Sr) A1-Li alloy were investigated by means of optical microscope, SEM and XRD. The results show that compared to the conventional solid solution treatment(540 ℃× 2 h) plus T8 aging( 121 ℃×14 h +151 ℃×48 h), enhanced solid solution(540 ℃× 2 h +550 ℃× 2.67 h) plus T8 aging can decrease coarse precipitated phases significantly, promote recrystallization, refine grains and increase the formation of equiaxed grains of the 2099-Sr Al-Li alloy. It is found that enhanced solid solution plus T8 aging decreases the resistance of intergranular corrosion, but improves the resistance of exfoliation corrosion for 2099-Sr Al-Li alloy.

参考文献

[1] DU Yu-xuan,ZHANG Xin-ming,YE Ling-ying,LUO Zhi-hui.Superplastic behavior of Al-Cu-Li based alloy[J].中国有色金属学会会刊(英文版),2006(z3):1379-1382.
[2] Romios M;Tiraschi R;Parrish C et al.Design of muhistep aging treatments of 2099 (C458) A1-Li alloy[J].Journal of Materials Engineering and Performance,2005,14(05):641-646.
[3] 魏修宇,郑子樵,佘玲娟,陈秋妮,李世晨.Mg、Zn在2099铝锂合金中的微合金化作用[J].稀有金属材料与工程,2010(09):1583-1587.
[4] 朱小辉,郑子樵,钟申.Mg和Zn对2099合金时效组织与拉伸性能的影响[J].中国有色金属学报,2010(10):1861-1867.
[5] 许晓静;王彬;吴桂潮 等.锶微合金化高锌2099型铝合金抗晶间腐蚀及剥蚀性能[J].稀有金属材料与工程,2011,40(z2):248-251.
[6] GB 7998-2005.铝合金晶间腐蚀测定方法[S].,2005.
[7] ASTM Gl10-1992 (1997).Standard practice for evaluating intergranular corrosion resistance of heat treatable aluminum alloys by immersion in sodium chloride + hydrogen peroxide solution[S].,1997.
[8] GB/T 22639-2008.铝合金加工产品的剥落腐蚀试验方法[S].,2008.
[9] ASTM G34-2001.Standard test method for exfoliation corrosion susceptibility in 2XXX and 7XXX series aluminum[S].,2001.
[10] Brown R H;Fink W L;Hunter M S .Measurement of irreversible potentials as a metallurgical research tool[J].Trans A1ME,1941,143:115-123.
[11] M aitra S;English G C .Mechanism of localized corrosion of 7075 alloy plate[J].Chemistry and Materials Transactions A,1981,12(03):535-541.
[12] Buchheit R G;Morgan J P;Stoner G E .Electrochemical behavior of the TI (A12 CuLi) intermetallic compound and its role in localized corrosion of A1-2% Li-3% Cu alloys[J].Corrosion,1994,50(02):120-131.
[13] 巢宏,陈康华,方华婵,肖代红.三级固溶处理对Al-Zn-Mg-Cu系铝合金组织和剥落腐蚀性能的影响[J].粉末冶金材料科学与工程,2009(03):179-183.
[14] 王月,吴庭翱.含钪Al-Mg合金的抗应力腐蚀和剥落腐蚀性能研究[J].中国腐蚀与防护学报,2005(04):218-221.
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