目前,时铝合金表面腐蚀行为的研究,宏观和微观脱离,不能精确地显示腐蚀结果.尝试利用体视显微镜技术对LY12CZ铝合金的腐蚀进行实时观测并重现腐蚀过程,对体视显微镜技术在腐蚀试验中的应用进行了探索.结果表明:在EXCO溶液中LY12CZ铝合金的腐蚀是从表面膜的破坏开始的,并且腐蚀坑总是沿着轧制方向(晶界方向)发展,即使有垂直于轧制方向的人为划痕也是如此;在特定条件下,不稳定的胶状Al(OH)3膜也能阻碍局部腐蚀的发展,初期先发生腐蚀的部住,往往并不是腐蚀最严重的部位.体视显微镜技术能够实现实时观测和表面腐蚀过程的重现,如果能克服其放大倍数等方面的限制,则有可能对腐蚀研究实现宏观与微观的结合,可以准确地展示腐蚀状况.
参考文献
[1] | 鲁自界 .LY12CZ和7075-T6铝合金在氯化钠溶液中的腐蚀疲劳裂纹扩展研究[D].中国科学院金属研究所,2001. |
[2] | 徐增华.金属耐蚀材料[J].腐蚀与防护,2001(01):46-48. |
[3] | Petroyiannis PV;Kermanidis AT;Papanikos P;Pantelakis SG .Corrosion-induced hydrogen embrittlement of 2024 and 6013 aluminum alloys[J].Theoretical and Applied Fracture Mechanics,2004(1/3):173-183. |
[4] | Weilong Zhang;G. S. Frankel .Transitions between pitting and intergranular corrosion in AA2024[J].Electrochimica Acta,2003(9):1193-1210. |
[5] | Shiling RUAN;Douglas A. WOLFE;Weilong ZHANG .Statistical Modeling of Minimum Intergranular Corrosion Path Length in High-Strength Aluminum Alloy[J].Technometrics,2004(1):69-75. |
[6] | Samuels B W;Sotoudeh K;Foley R T .Inhibition and acceleration of aluminum corrosion[J].Corrosion,1981,37(02):92-97. |
[7] | Bellinger NC.;Gould RW.;Komorowski JP. .Damage tolerance implications of corrosion pillowing on fuselage lap joints[J].Journal of aircraft,1998(3):487-491. |
[8] | Jones R;Pitt S;Molent L .Study of multi-site damage of fuselage lap joints[J].Theoretical and Applied Fracture Mechanics,1999(2):81-100. |
[9] | Kinzie R.Improved Corrosion Maintenance Practice[A].Manchester:NATO,2001:8-11. |
[10] | X. Zheng .A Novel Model for Crevice Corrosion of Lap Joints[J].Corrosion: The Journal of Science and Engineering,2001(7):634-642. |
[11] | K. S. Ferrer;R. G. Kelly .Development of an Aircraft Lap Joint Simulant Environment[J].Corrosion: The Journal of Science and Engineering,2002(5):452-459. |
[12] | Wei R P;Liao C M;Gao M .A Transmission Electron Microscopy Study of Constituent-Particle-Induced Corrosion in 7075-T6 and 2024-T3 Aluminum Alloys[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1998,29A(01):1153-1160. |
[13] | Petroyiannis PV;Pantelakis SG;Haidemenopoulos GN .Protective role of local Al cladding against corrosion damage and hydrogen embrittlement of 2024 aluminum alloy specimens[J].Theoretical and Applied Fracture Mechanics,2005(1):70-81. |
[14] | Rashkeev SN;Sohlberg KW;Zhuo SP;Pantelides ST .Hydrogen-induced initiation of corrosion in aluminum[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(19):7175-7178. |
[15] | Gamal A. EL-Mahdy;Kwang B. Kim .AC impedance study on the atmospheric corrosion of aluminum under periodic wet-dry conditions[J].Electrochimica Acta,2004(12):1937-1948. |
[16] | Szklarska-Smialowska Z .Mechanism of pit nucleation by electrical breakdown of the passive film[J].Corrosion Science,2002,44(05):1143-1149. |
[17] | 杨振海,徐宁,邱竹贤.铝的电位-pH图及铝腐蚀曲线的测定[J].东北大学学报(自然科学版),2000(04):401-403. |
[18] | Guillaumin V;Mankowski G .Localized corrosion of 2024 T351 aluminum alloy in chloride media[J].Corrosion Science,1999,41(03):421-438. |
[19] | Posada M;Murr L E .Exfoliation and related microstructures in 2024 aluminum body skins on aging aircraft[J].Materials Characterization,1997,38(4,5):259-272. |
[20] | Paglia CS;Buchheit RG .Microstructure, microchemistry and environmental cracking susceptibility of friction stir welded 2219-T87[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2006(1-2):107-114. |
[21] | Paglia CS;Jata KV;Buchheit RG .A cast 7050 friction stir weld with scandium: microstructure, corrosion and environmental assisted cracking[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2006(1-2):196-204. |
[22] | 王轶农,武保林,王刚,蒋奇武,赵骧,左良.LY12铝合金的再结晶织构、晶界特征分布及抗腐蚀性能[J].金属学报,2000(10):1085-1088. |
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