Ni-B非晶态合金作为一种新型的催化材料,具有较高的催化活性和选择性,且易于制备,受到了众多化学工作者的重视.本文简要地介绍了制备Ni-B非晶态催化剂的化学还原方法和机理,并且讨论了载体、退火晶化行为、稀土改性等对催化剂的活性、热稳定性和抗硫中毒性的影响.最后展望了Ni-B非晶态催化剂在工业上的应用前景.
参考文献
| [1] | Smith G V;Brower W E.Proc 7th Int Congr Catal[M].Tokyo,1980:355. |
| [2] | Jacques Van Wonterghem;Steen Morup;Christian J W Koch et al.[J].NATURE,1986,322:622. |
| [3] | Yamashita H;Yoshikawa M;Kaminade T et al.[J].Journal of the Chemical Society,Faraday Transactions 1,1986,82(03):707. |
| [4] | Deng J F;Zhang X .[J].Applied Catalysis,1988,37:339. |
| [5] | Molnar A;Smith G V;Bartok M .[J].Advances in Catalysis,1989,36(02):329-367. |
| [6] | 宗保宁,慕旭宏,孟祥堃,张晓昕,汪颖,闵恩泽.镍基非晶态合金加氢催化剂与磁稳定床反应器的开发与工业应用[J].化工进展,2002(08):536-539. |
| [7] | Deng Jing-Fa;Li Hexing;Wang Weijiang .Progress in design of new amorphous alloy catalysts[J].Catalysis Today,1999,51:113-125. |
| [8] | Xia WS.;Jiang YS.;Chen Y.;Fan Y. .LOCAL SURFACE STATE OF AMORPHOUS NIP AND NIB ALLOY CATALYSTS[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,1996(1):1-9. |
| [9] | 方志刚,沈百荣,陆靖,范康年,邓景发.Ni-B非晶态合金中电子转移问题的DFT研究[J].化学学报,1999(08):894-900. |
| [10] | Linderoth S;Morop S .[J].Journal of Applied Physics,1991,69:52-56. |
| [11] | 沈俭一;李智渝;陈懿 .Ni-B超细非晶合金的化学制备、反应机理及性质研究[J].无机化学学报,1995,11(01):1-6. |
| [12] | 李同信;张秀峰;李合秋 等.非晶态超微粒子镍合金催化剂的研究Ⅰ.Ni-B合金的制备及表征[J].催化学报,1995,16(04):299-303. |
| [13] | 石秋杰,陈昭萍,罗来涛,李凤仪,王祥生.海泡石对非晶态NiB合金催化剂的改性研究[J].物理化学学报,2000(06):501. |
| [14] | 刘波,陈雪莹,庄继华,乔明华,曹勇,朱源龙,贺鹤勇,范康年.负载型Ni-B非晶态合金的制备及其催化加氢活性研究[J].复旦学报(自然科学版),2002(04):424-428. |
| [15] | 石秋杰;李凤仪;罗来涛 .γ-Al2O3对NiB合金的催化及表面性能的影响[J].物理化学学报,1998,14(07):635-639. |
| [16] | 马爱增.负载型Ni-B非晶态合金催化剂的表征及催化性能[J].催化学报,1999(06):603-607. |
| [17] | Wang Wei-jiang;Qiao Ming-hug;Yang Jun et al.Selective hydrogenation of cyclopentadiene to cyclopentene over an amorphous Ni-B/SiO2 catalyst[J].Applied Catalysis A:General,1997,163:101-107. |
| [18] | 韦世强,王晓光,殷士龙,陈昌荣,刘文汉,张新夷.NiB和NiP超细非晶态合金的退火晶化行为及催化性能[J].催化学报,2001(02):113-118. |
| [19] | Rojo J M;Hernando A;Ghannami M E et al.[J].Physical Review Letters,1996,76(25):4833. |
| [20] | Riveiro J M;Muniz P;Andres J P et al.[J].Journal of Magnetism and Magnetic Materials,1998,188(1-2):153. |
| [21] | 韦世强,李忠瑞,张新夷,陈昌荣,刘文汉,胡天斗,谢亚宁,刘涛,王晓光.超细Ni-B非晶态合金的退火晶化及其催化性能[J].科学通报,2000(18):1941-1944. |
| [22] | 韦世强,张新夷,刘文汉,王晓光,杨宏伟,闫文胜.退火晶化过程中Ni-B纳米非晶态合金的结构[J].物理化学学报,2001(08):750-752. |
| [23] | 王晓光,张新夷,李忠瑞,钟文杰,贺博,韦世强.Ni-B和Ni-Ce-B超细非晶态合金的退火晶化及其催化性能[J].催化学报,2001(04):397-401. |
| [24] | Rongbin Zhang;Fengyi Li;Qiujie Shi .The effects of rare earths on supported amorphous NiB/Al_2O_3 catalysts[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2001(1/2):279-284. |
| [25] | 李凤仪,张荣斌,石秋杰,罗来涛.稀土在负载型非晶态NiB/Al2O3合金上作用研究[J].稀土,2000(04):38-42. |
| [26] | 石秋杰;李凤仪;罗来涛 等.轻稀土氧化物对非晶态NiB合金催化剂的改性研究[J].分子催化,1999,13(01):9-14. |
| [27] | 石秋杰;张雪红;李凤仪 等.钐对非晶态NiB合金催化剂性能及表面性质的影响[J].催化学报,1998,19(04):295-299. |
| [28] | 马爱增,陆婉珍,闵恩泽.含金属添加剂的负载型NiB非晶态合金催化剂的结构及催化性能[J].石油化工,2000(03):179-183. |
| [29] | 唐忠,张帆,陶庭树,冯仰渝.Ni-Cu-B非晶态合金催化剂对双烯选择性加氢性能的研究[J].石油化工,2000(10):754-756. |
| [30] | Yu Zhong-bin;Qiao Ming-hua;Li He-xing et al.Preparation of amorphous Ni-Co-B alloys and the effect of cobalt on their hydrogenation activity[J].Applied Catalysis A:General,1997,163:1-13. |
| [31] | 杨军.纳米Ni-B非晶态合金的催化性质研究[J].高等学校化学学报,1994(12):1848. |
| [32] | 马爱增;陆婉珍;闵恩泽 .非晶态合金催化剂对乙烯中微量乙炔的选择加氢[J].石油学报,1996,12(02):29-37. |
| [33] | Wei-Jiang Wang;He-Xing Li;Song-Hai Xie;Yong-Jiang Li;Jing-Fa Deng .Regeneration at room temperature for amorphous NiB/SiO_2 catalyst deactivated in cyclopentadiene hydrogenation[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,1999(1):33-39. |
| [34] | 杨军;柴亮;邓景发 等.非晶态合金作催化剂的研究Ⅳ,超细非晶态Ni-B催化剂的制备及催化性能研究[J].化学学报,1994,52:53-58. |
| [35] | Rongbin Zhang;Fengyi Li;Ning Zhang;Qiujie Shi .Benzene hydrogenation over amorphous NiB/bentonite catalyst and promoting effect of Nd[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2003(1/2):17-23. |
| [36] | Li Jiang;Qiao Minghua;Deng Jingfa .Amorphous Ni-B/γ -Al2O3 catalyst prepared in modified drying approach and its excellent activity in benzene hydrogenation[J].Journal of Molecular Catalysis A:Chemical,2001,169:295-301. |
| [37] | 王鹏;李辉;曹勇 等.负载型非晶态合金催化剂(Ni-B/SiO2)与己二腈气固相常压加氢的研究[J].复旦学报(自然科学版),1999,38(01):2-6. |
| [38] | Li Hexing;Xu Yeping;Li Hui et al.Gas-phase hydrogenation of adiponitrile with high selectivity to primary amine over supported Ni-B amorphous catalysts[J].Applied Catalysis A:General,2001,216:51-58. |
| [39] | 王明辉,李和兴.Ni-B/SiO2非晶态催化剂应用于硝基苯液相加氢制苯胺[J].催化学报,2001(03):287-290. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%