利用阴阳离子交换膜变电流电解方法, 研究了改变电流密度条件下将混合硫酸稀土溶液中Ce(Ⅲ)电解氧化为Ce(Ⅵ)时, 电流密度和电解时间对阳极电流效率和Ce(Ⅲ)氧化率的影响. 结果表明: 阴离子交换膜体系中, 在相同电解电量条件下, 电流效率和氧化率随平均电流密度升高而降低; 当电流效率达到80%时, 电流密度和铈离子浓度有线性关系; 平均电流密度为325.A/m2的电流密度组合有较高的电流效率和氧化率; 电解时间相同时, 每一个电流密度电解时间越短, 越有利于提高电流效率, 电解后期适当延长低电流密度电解时间可以使Ce(Ⅲ)的氧化率达到99%; 在阳离子交换膜电解体系中, 电流效率达到80%时, 电流密度和Ce3+离子浓度无线性关系.
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