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在模拟压水堆一回路水环境中,对镍基690合金进行了在加锌量分别为10,60,120 μg/L的三组320℃高温溶液中600 h的腐蚀试验,并对腐蚀后的试样表面进行了X射线光电子能谱(XPS)分析.结果表明,随着锌浓度的增加,试样的腐蚀增重速率降低,氧化膜厚度减薄,降低腐蚀速率的有效加锌量范围为10~60μg/L;试样表面形成主要成分为ZnCr2O4和Cr2O3的氧化膜.

参考文献

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[2] H. Kawamura;H. Hirano;S. Shirai;H. Takamatsu;T. Matsunaga;K. Yamaoka;K. Oshinden;H. Takiguchi .Inhibitory effect of zinc addition to high-temperature hydrogenated water on mill-annealed and prefilmed alloy 600[J].Corrosion: The Journal of Science and Engineering,2000(6):623-637.
[3] Junbo Huang;Xiahe Liu;En-Hou Han;Xinqiang Wu .Influence of Zn on oxide films on Alloy 690 in borated and lithiated high temperature water[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2011(10):3254-3261.
[4] 乔培鹏,张乐福,刘瑞芹,姜苏青,朱发文.压水堆条件下锌对奥氏体不锈钢腐蚀性能的影响[J].原子能科学技术,2010(06):690-693.
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