Zn2+对304L不锈钢钝化膜半导体性能的影响目前鲜见报道.利用电容测量法研究了304L不锈钢在一系列ZnSO4浓度溶液中所形成的钝化膜的半导体性能,同时对影响钝化膜半导体性能的因素进行了讨论.考虑SO24-对不锈钢钝化膜的影响,在相同温度和浓度的条件下进行了Na2SO4中的浸泡对比试验.结果表明:在电位小于-0.4 V内,膜呈p型半导体特性,电位处于-0.4～0.3 V内,膜呈n型半导体特性;随着测试温度的升高及Zn2+浓度的增加,Mott-Sclaottky曲线的斜率有增大的趋势,膜内的杂质浓度减小.
参考文献
| [1] | Michael A .Streicher Alloying Stainless Steels with the Platinum[J].Metals Platinum Metals Rev,1977,21(02):51-55. |
| [2] | M. Da Cunha Belo;N. E. Hakiki;M. G. S. Ferreira .Semiconducting properties of passive films formed on nickel-base alloys type alloy 600: influence of the alloying elements[J].Electrochimica Acta,1999(14):2473-2481. |
| [3] | J. W. Schultze;M. M. Lohrengel .Stability, reactivity and breakdown of passive films. problems of recent and future research[J].Electrochimica Acta,2000(15/16):2499-2513. |
| [4] | Fruzzetti K.PWR Zinc Application Guidelines[M].Electric Power Research Institute,2006 |
| [5] | Dewald J F .The charge distribution at the zinc oxide-electrolyte interface[J].Journal of Physics and Chemistry of Solids,1960,14:155-161. |
| [6] | Bachler M;Sehmuki P;Hni H B .A light reflectance technique for thickness measurements of passive films[J].Electrochimica Acta,1997,43(5,6):635-637. |
| [7] | Janusz Sikora;Elzbieta Sikora;Digby D. Macdonald .The electronic structure of the passive film on tungsten[J].Electrochimica Acta,2000(12):1875-1883. |
| [8] | Schmuki P;Bohui H .Illumination effects on the stability of the passive on iron[J].Electrochimica Acta,1995,40(06):775-783. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%