The characteristics of mc-Si used for solar cells during H2 ambient annealing at 800-1200 ℃ were investigated by means of FTIR and QSSPCD. The results reveal that grain boundaries or defects in mc-Si may facilitate the formation of oxygen precipitates, and the formation of oxygen precipitates has deleterious effect on the lifetime of mc-Si. Decreasing lifetime could result from the formation of new recombination during annealing. Additionally, It is found that hydrogen may facilitate the formation of oxygen precipitates in mc-Si. On the other hand, the diffusion of hydrogen may passivate the defects/boundaries and it is beneficial to the lifetime of mc-Si.
参考文献
[1] | Mimura M.;Saitoh T.;Ishikawa S. .Effect of thermal annealing on minority-carrier lifetimes in multicrystalline Si wafers[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(1/4):459-463. |
[2] | Moller H J;Funke C.Oxygen and lattice distortions in multicrystalline silicon[M]. |
[3] | Kang J S et al.Gettering in silicon[J].Journal of Applied Physics,65(08):2974. |
[4] | Yu Zhengfeng.Study on oxygen defect of multicrystalline silicon[M].杭州:浙江大学 |
[5] | Yang DR.;Li DS.;Wang LR.;Ma XY.;Que DL. .Oxygen in Czochralski silicon used for solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1/4):133-138. |
[6] | Newman R C .Oxygen diffusion and precipitation in CZ silicon[J].J Phys:Condents Matter,2000,12:R335. |
[7] | Prakash, Om;Singh, S. .Oxygen related donors in Czochralski-grown silicon annealed at 465-650 deg C[J].The journal of physics and chemistry of solids,1999(3):353-358. |
[8] | Li Huaixiang;Xue Chengshan .Hydrogen catalyzed oxygen precipitate in crystalline silicon[J].Journal of Shandong Normal University(Natural Science),1998,13(03):271. |
[9] | 王晓泉,杨德仁,余学功,马向阳,阙端麟.氢退火对掺氮硅中氧施主电学行为的影响[J].材料科学与工程学报,2003(03):353-355. |
[10] | Elgamel HEA.;Mertens R.;Mauk MG.;Barnett AM.;Nijs J. .Hydrogen in polycrystalline silicon solar cell material: Its role and characteristics[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1998(3/4):277-284. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%