可控活性自由基聚合(CRP)是一种合成具有设计微观结构和窄分子量分布聚合物的方法,原子转移自由基聚合(ATRP)较其它CRP方法具有分子设计能力较强等优点,是应用最广泛的CRP.文中简要介绍了CRP的分类,同时以ATRP为例从单体、引发剂、催化体系等方面讨论了CRP聚合体系的发展.
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