研究了由TiO_2颗粒和TiO_2溶胶组成的复合TiO_2溶胶,以及其电泳制备涂层的光催化性.实验发现复合溶胶的Zeta电位小于相应的溶胶Zeta电位.对于溶胶在不同温度下煅烧制备的TiO_2粉末进行XRD表征,结果表明随着煅烧温度升高,粉末结晶程度提高,从200 ℃开始出现锐钛矿TiO_2晶相,在550 ℃出现金红石型TiO_2.光催化性能表明,由溶胶而得到的TiO_2涂层的光催化性能要好于复合TiO_2溶胶的光催化性能.
Composite TiO_2 sol composed of TiO_2 particles and TiO_2 sol was prepared, and photocatalytic properties of the coatings prepared by electrophoresis deposition were investigated. It was revealed that zeta potential of composite TiO_2 sol was smaller than that of corresponding TiO_2 sol. The TiO_2 powder was prepared by firing the TiO_2 sol at different temperatures. The results show that higher temperatures improve the titania crystallinity. Anatase TiO_2 peaks appear at 200 ℃, and rutile TiO_2 peaks appear at 550 ℃. The experiments of photocatalytic properties show the photocatalytic properties of sol are better than that of composite TiO_2 sol.
参考文献
[1] | Fernandez A;Lassaletta G;Jimenez V M et al.[J].Applied Catalysis B:Environmental,1995,7:49. |
[2] | Mohd;Asri Nawi;Lim Choo Kean et al.[J].Applied Catalysis B:Environmental,2003,46:165. |
[3] | 卢晓平,戴文新,王绪绪,付贤智,邵宇,刘平,李旦振.TiO2胶粒在铝合金表面的电泳沉积及所制薄膜的光催化性能研究[J].无机化学学报,2004(06):734-738. |
[4] | Byrne J A;Eggins B R;Brown N M D et al.[J].Applied Catalysis B:Environmental,1998,17:25. |
[5] | Mehrdad Keshmiri .[D].London:The University of British Columbia,2004. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%