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采用凝胶注模技术原位合成造孔剂制备出开孔气孔率为20%~30%的La0 8Sr0.2MnO3多孔阴极材料.结果表明,合适的烧结温度为1 100℃~l150℃;开口气孔位于三角晶界,中位孔径约为400 nm;多孔材料的电导率随着温度的升高而升高,由ln(σT)~l/T曲线,可得电导活化能Ea为10.99 kJ/mol.

参考文献

[1] Minh N Q .Ceramic Fuel Cells[J].Journal of the American Ceramic Society,1993,76(03):563-588.
[2] Srilomsak S;Schilling D P;Sparlin D M.Proceedings of the First International Symposium on Oxide Fuel Cells[A].New Jersey:Pennington Press,1989:129.
[3] de Haart L G;Kuipers R A et al.Deposition and Electrical Properties of Thin Porous Ceramic Layers for SOFC Application[J].Journal of the Electrochemical Society,1991,138(07):1970-1975.
[4] Taimatsu H;Wada K;Kaneko H et al.Mechanism of Reaction between Lanthanum Manganite and Yttria-Stabilized Zirconia[J].Journal of the American Ceramic Society,1992,75:401-405.
[5] Otoshi S;Sasaki H;Ohnishi H et al.Changes in the Phase and Electrical Conduction Properties of (La1-xSrx)1-yMnO3-δ[J].Journal of the Electrochemical Society,1991,138:1519-1523.
[6] 夏长荣,许大刚,高建峰,孟广耀,彭定坤.多孔La1-xSrxMnO3的制备及表征[J].功能材料,2001(03):269-271.
[7] Ometete O O;Janney M A;Strehlow R A .Gelcasting-A New Ceramic Forming Process[J].Ceramic Bulletin,1991,70(10):1641-1649.
[8] Carisey T;Werth A L;Brandon D G .Control of Texture in A12O3 by Gelcasting[J].Journal of the European Ceramic Society,1995,15:1-6.
[9] Baskin D M;Zimmerman M H;Faber K T .Forming SinglePhase Laminates via the Gelcasting Technique[J].Journal of the American Ceramic Society,1991,74(03):612-617.
[10] Wang H T;Liu X Q et al.Porous α-Al2O3 Ceramics Prepared by Gelcasting[J].Materials Research Bulletin,1997,32(12):1705-1712.
[11] 仝建峰 .氮化铝陶瓷基片碳热还原低成本制备技术研究[D].北京:北京航空学院,2002.
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