投加二氧化氯可以有效地控制冷却水中的微生物。采用旋转挂片腐蚀试验和电化学试验研究了二氧化氯对金属的腐蚀问题，并研究了二氧化氯溶液中配伍羧酸类水处理剂PBTCA（2-膦酸基丁烷-1，2，4-三羧酸）、PESA（聚环氧琥珀酸）、TH-628（有机羧酸复合药剂）的缓蚀性能。结果表明，二氧化氯浓度为0．8mg／L时，碳钢的腐蚀率最低。三种药剂在二氧化氯的体系中均有一定的缓蚀作用，PESA的缓蚀效果最好。在碳钢的腐蚀过程中，复合药剂TH-628对电极的阳极和阴极过程均具有抑制作用，属于混合型缓蚀剂。
Microorganisms in circulating cooling water can be effectively controlled by injecting chlorine dioxide. The metal corrosion due to chlorine dioxide and the corrosion inhibition property of PBTCA (2-phosphonobutane-1, 2, 4- tricarboxylic acid), PESA (polyepoxysuccinic acid) and TH-628(organic carboxylic acid complex reagent) in chlorine dioxide solution were investigated by rotary weight-loss measurement and electrochemical testing. The results indicated that the concentration of 0. 8 mg/L chlorine dioxide resulted in the lowest corrosive rate of carbon steel. Complex drugs TH-628, PBTCA and PESA had good inhibition effects. In the process of corrosion of carbon steel, complex reagent TH-628 has inhibition effect on the reactions of both anode and cathode. So it is a mixed inhibitor.
参考文献
| [1] | 段杨萍,胡跃华,段青兵,余立坤.过氧乙酸用于循环冷却水系统杀菌的试验研究[J].化工进展,2005(06):676-681. |
| [2] | 余光勇.敞开式循环冷却水中微生物控制方法的探析[J].工业水处理,2008(12):88-90. |
| [3] | 张丽华,郑成松,张严,王仁章.环境友好聚环氧琥珀酸的研究进展[J].工业水处理,2010(05):5-8. |
| [4] | 滕玉洁,邵曙海,崔崇威,焦雅吉,张杰.二氧化氯和有机膦药剂的配伍性能研究[J].哈尔滨商业大学学报（自然科学版）,2008(03):313-315,354. |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%