采用BNi2钎料实现了TiAl基合金与Ni基高温合金的钎焊.采用扫描电镜、能谱分析和X射线衍射等手段对钎焊接头的界面组织结构及生成相进行分析,并对接头的抗剪强度进行测试.结果表明,钎焊接头的典型界面结构为:GH99/(Ni)ss (γ)+Ni3B+CrB+富Ti-硼化物/TiNi2Al/TiNiAl+ Ti3Al/TiAl;随着钎焊温度的升高或保温时间的延长,较多的B和Si元素扩散进入两侧母材,导致钎缝中硼化物数量减少,而TiAl/钎缝界面的TiNi2Al和TiNiAl+Ti3Al金属间化合物层厚度增加;当钎焊温度为1050℃,保温时间为5 min时,接头的抗剪强度达到最大为205 MPa,接头主要断裂于TiNiAl金属间化合物层.当钎焊温度升高或保温时间继续延长时,TiNiA1厚度显著增加,导致接头强度下降.
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