首先简单介绍了石墨烯的结构、性能和制备方法,然后着重阐述了石墨烯/半导体复合结构在光解水产氢、降解污染物、转化CO2这3个光催化方面的应用研究.最后从半导体的选择、复合工艺的改进、石墨烯功能化3个角度对研究过程中存在的问题提出了展望.
参考文献
[1] | Fujishima A;Honda K .Photolysis-decomposition of water at the surface of an irradiated semiconductor[J].NATURE,1972,238(5385):37. |
[2] | Chen, X.;Shen, S.;Guo, L.;Mao, S.S. .Semiconductor-based photocatalytic hydrogen generation[J].Chemical Reviews,2010(11):6503-6570. |
[3] | Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].SCIENCE,2004,306(5696):666. |
[4] | 朱宏伟;徐志平;谢丹.石墨烯-结构、制备方法与性能表征[M].北京:清华大学出版社,2011:13. |
[5] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
[6] | Changgu Lee;Xiaoding Wei;Jeffrey W. Kysar;James Hone .Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J].Science,2008(5887):385-388. |
[7] | Balandin AA;Ghosh S;Bao WZ;Calizo I;Teweldebrhan D;Miao F;Lau CN .Superior thermal conductivity of single-layer graphene[J].Nano letters,2008(3):902-907. |
[8] | Nair RR;Blake P;Grigorenko AN;Novoselov KS;Booth TJ;Stauber T;Peres NM;Geim AK .Fine structure constant defines visual transparency of graphene.[J].Science,2008(5881):1308-1308. |
[9] | Bolotin, KI;Sikes, KJ;Jiang, Z;Klima, M;Fudenberg, G;Hone, J;Kim, P;Stormer, HL .Ultrahigh electron mobility in suspended graphene[J].Solid State Communications,2008(9/10):351-355. |
[10] | 张伟娜,何伟,张新荔.石墨烯的制备方法及其应用特性[J].化工新型材料,2010(z1):15-18,131. |
[11] | Li D;Muller MB;Gilje S;Kaner RB;Wallace GG .Processable aqueous dispersions of graphene nanosheets[J].Nature nanotechnology,2008(2):101-105. |
[12] | Hummers Jr W S;Offeman R E .Preparation of graphitic oxide[J].Journal of the American Chemical Society,1958,80(06):1339. |
[13] | Xu, YX;Bai, H;Lu, GW;Li, C;Shi, GQ .Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets[J].Journal of the American Chemical Society,2008(18):5856-5857. |
[14] | Marcano DC;Kosynkin DV;Berlin JM;Sinitskii A;Sun ZZ;Slesarev A;Alemany LB;Lu W;Tour JM .Improved Synthesis of Graphene Oxide[J].ACS nano,2010(8):4806-4814. |
[15] | Xiao-Yan Zhang;Hao-Peng Li;Xiao-Li Cui .Graphene/TiO2 nanocomposites: synthesis, characterization and application in hydrogen evolution from water photocatalytic splitting[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(14):2801-2806. |
[16] | Wenqing Fan;Qinghua Lai;Qinghong Zhang .Nanocomposites of TiO2 and Reduced Graphene Oxide as Efficient Photocatalysts for Hydrogen Evolution[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(21):10694-10701. |
[17] | Mukherji, A;Seger, B;Lu, GQ;Wang, LZ .Nitrogen Doped Sr(2)Ta(2)O(7) Coupled with Graphene Sheets as Photocatalysts for Increased Photocatalytic Hydrogen Production[J].ACS nano,2011(5):3483-3492. |
[18] | Iwase, A.;Ng, Y.H.;Ishiguro, Y.;Kudo, A.;Amal, R. .Reduced graphene oxide as a solid-state electron mediator in Z-scheme photocatalytic water splitting under visible light[J].Journal of the American Chemical Society,2011(29):11054-11057. |
[19] | Li, Q.;Guo, B.;Yu, J.;Ran, J.;Zhang, B.;Yan, H.;Gong, J.R. .Highly efficient visible-light-driven photocatalytic hydrogen production of CdS-cluster-decorated graphene nanosheets[J].Journal of the American Chemical Society,2011(28):10878-10884. |
[20] | Xiang, Q.;Yu, J.;Jaroniec, M. .Synergetic effect of MoS _2 and graphene as cocatalysts for enhanced photocatalytic H _2 production activity of TiO _2 nanoparticles[J].Journal of the American Chemical Society,2012(15):6575-6578. |
[21] | Aihua Ye;Wenqing Fan;Qinghong Zhang .CdS-graphene and CdS-CNT nanocomposites as visible-light photocatalysts for hydrogen evolution and organic dye degradation[J].Catalysis science & technology,2012(5):969-978. |
[22] | Zhang J;Yu J;Jaroniec M et al.Noble metal-free reduced graphene oxide-Znx Cdi-xS nanocomposite with enhanced solar photocatalytic H2-production performance[J].NANO LETTERS,2012,12(09):4584. |
[23] | Li Jia;Dong-Hong Wang;Yu-Xi Huang .Highly Durable N-Doped Graphene/CdS Nanocomposites with Enhanced Photocatalytic Hydrogen Evolution from Water under Visible Light Irradiation[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(23):11466-11473. |
[24] | Quanjun Xiang;Jiaguo Yu;Mietek Jaroniec .Preparation and Enhanced Visible-Light Photocatalytic H2-Production Activity of Graphene/C3N4 Composites[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(15):7355-7363. |
[25] | Te-Fu Yeh;Jhih-Ming Syu;Ching Cheng;Ting-Hsiang Chang;Hsisheng Teng .Graphite Oxide as a Photocatalyst for Hydrogen Production from Water[J].Advanced functional materials,2010(14):2255-2262. |
[26] | Quanjun Xiang;Jiaguo Yu;Mietek Jaroniec .Graphene-based semiconductor photocatalysts[J].Chemical Society Reviews,2012(2):782-796. |
[27] | Jungang Hou;Zheng Wang;Wenbin Kan .Efficient visible-light-driven photocatalytic hydrogen production using CdS@TaON core-shell composites coupled with graphene oxide nanosheets[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(15):7291-7299. |
[28] | Zhang, Y.;Tang, Z.-R.;Fu, X.;Xu, Y.-J. .TiO2-graphene nanocomposites for gas-phase photocatalytic degradation of volatile aromatic pollutant: Is TiO2-graphene truly different from other TiO2-carbon composite materials?[J].ACS nano,2010(12):7303-7314. |
[29] | 应红,王志永,郭政铎,施祖进,杨上峰.还原氧化石墨烯修饰Bi2WO6提高其在可见光下的光催化性能[J].物理化学学报,2011(06):1482-1486. |
[30] | Yongsheng Fu;Xin Wang .Magnetically Separable ZnFe2O4-Graphene Catalyst and its High Photocatalytic Performance under Visible Light Irradiation[J].Industrial & Engineering Chemistry Research,2011(12):7210-7218. |
[31] | Gao E;Wang W;Shang M et al.Synthesis and enhanced photocatalytic performance of graphene-Bi2WO6 composite[J].Physical Chemistry Chemical Physics,2011,13(07):2887. |
[32] | Baojun Li;Huaqiang Cao .ZnO@graphene composite with enhanced performance for the removal of dye from water[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(10):3346-3349. |
[33] | Jintao Zhang;Zhigang Xiong;X. S. Zhao .Graphene-metal-oxide composites for the degradation of dyes under visible light irradiation[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(11):3634-3640. |
[34] | Xiong, Z.;Zhang, L.L.;Ma, J.;Zhao, X.S. .Photocatalytic degradation of dyes over graphene-gold nanocomposites under visible light irradiation[J].Chemical communications,2010(33):6099-6101. |
[35] | Zhang, L.L.;Xiong, Z.;Zhao, X.S. .Pillaring chemically exfoliated graphene oxide with carbon nanotubes for photocatalytic degradation of dyes under visible light irradiation[J].ACS nano,2010(11):7030-7036. |
[36] | Liang, Y.T.;Vijayan, B.K.;Gray, K.A.;Hersam, M.C. .Minimizing graphene defects enhances titania nanocomposite-based photocatalytic reduction of CO_2 for improved solar fuel production[J].Nano letters,2011(7):2865-2870. |
[37] | Lv X J;Fu W F;Hu C Y et al.Photocatalytic reduction of CO2 with H2O over a graphene-modified NiOx-Ta2 O5 composite photocatalyst:Coupling yields of methanol and hydrogen[J].RSC Advances,2013,3(06):1753. |
[38] | Wenguang Tu;Yong Zhou;Qi Liu;Zhongp'mg Tian;Jun Cao;Xiaoyu Chen;Haitao Zhang;Jianguo Liu;Zhigang Zou .Robust Hollow Spheres Consisting of Alternating Titania Nanosheets and Graphene Nanosheets with High Photo-catalytic Activity for CO_2 Conversion into Renewable Fuels[J].Advanced functional materials,2012(6):1215-1221. |
[39] | Ng Y H;Iwase A;Kudo A et al.Reducing graphene oxide on a visible-light BiVO4 photocatalyst for an enhanced photoelectrochemical water splitting[J].Journal of Physical Chemistry Letters,2010,1(17):2607. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%