对TA2工业纯Ti微弧氧化陶瓷膜的生长规律进行了实验研究,分析了陶瓷膜表面形貌、厚度、相结构等不同生长阶段的实验现象及结果。模拟微弧氧化工艺反应过程,运用多种理论建立并分析了氧化陶瓷膜生长模型及等效电路。模型及电路分析结果证明,陶瓷膜在形成时呈现先离散分布后连接成片的生长特点,成膜后TiO2陶瓷膜具有交流耦合电容效应。模型及等效电路分析与实验结果是吻合的,为改善TA2工业纯Ti微弧氧化工艺并提高陶瓷膜性能提供了实验与理论基础。
Experiments on the rules of ceramic coating growth were conducted in the process of pure titaniumTA2 microarc oxidation (MAO). The surface morphology, thickness and phase component in different stages were also analysed. Based on oxidation process and dielectric theories, theoretical model and equivalent circuit were established. The analysis results show that the ceramic coating distributes in fragmentation firstly and then in connection, and the completed TiO2 ceramic coating has alternating current (AC) coupling capacitor effect. All the analysis agrees with the experimental results, and it can provide a theoretical and experimental base for improving the performance of coatings as well as MAO technologies.
参考文献
[1] | Lebedeva I L;Presnyakova G N .Adhesion wear mecha- nisms under dry friction of titanium alloys in vaeuum[J].Wear,1991,148(02):203-210. |
[2] | I.iu Fu;Song Ying;Wang Fuping et al.Hydroxyapatite precipitation on Ti by microarc oxidation and hydrother- real treatment[J].Journal of Functional Materials,2006,37(01):127-129. |
[3] | Xue Wenbin;Wang Chao;Li Yongliang et al.Effect of microarc discharge surface treatment on the tensile prop- erties of AbCu-Mg alloy[J].Materials Letters,2002,56(05):737-743. |
[4] | Liu XY;Chu PK;Ding CX .Surface modification of titanium, titanium alloys, and related materials for biomedical applications[J].Materials Science & Engineering, R. Reports: A Review Journal,2004(3/4):49-121. |
[5] | Yerokhin A I;Nie X;Leyland A et al.Characterisation of oxide films produced by plasma electrolytic oxidation of a Ti6AI4V alloy[J].Surface and Coatings Technology,2000,130(2-3):195-206. |
[6] | 陈宏,郝建民,冯忠绪.微弧氧化机理及电击穿模型[J].长安大学学报(自然科学版),2008(05):116-119. |
[7] | P.I. Butyagin;Ye.V. Khokhryakov;A.I. Mamaev .Microplasma systems for creating coatings on aluminium alloys[J].Materials Letters,2003(11):1748-1751. |
[8] | Vangolu, Y.;Arslan, E.;Totik, Y.;Demirci, E.;Alsaran, A. .Optimization of the coating parameters for micro-arc oxidation of Cp-Ti[J].Surface & Coatings Technology,2010(6):1764-1773. |
[9] | 朱瑞富,王志刚,王宏元,肖桂勇,吕宇鹏,塙隆夫,小林郁夫.氧化时间对纯钛表面微弧氧化膜结构特性的影响[J].硅酸盐学报,2011(11):1825-1829. |
[10] | 李翰如.电介质物理导论[M].成都:成都科技大学出版社,1990:386-392. |
[11] | A. I. Mamaev;Yu. YU. Chekanova;Zh. M. Ramazanova .Parameters of Pulsating Microplasma Processes on Aluminum and Its Alloys[J].Protection of metals,2000(6):605-608. |
[12] | 王宏元,朱瑞富,王志刚,吕宇鹏,肖桂勇,朱先俊.纯钛微弧氧化阳极工艺过程模型的建立及实验研究[J].材料工程,2012(07):34-38. |
[13] | 王志刚 .纯钛表面多孔化及生物活化的研究[D].山东大学,2006. |
[14] | Jiang Zhaohua;Sun Xuetong;Li Yanping et al.Effect of the oxidation time on properties of ceramic coatings produced on Ti-6AI-4V by micro-arc oxidation[J].Journal of Materials Science and Technology,2005,21(02):281-284. |
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