磁场在未来可能成为一种主要的防腐蚀方法,从腐蚀速率、腐蚀形貌、传质速率、自腐蚀状态、阳极溶解和阴极去极化等几个方面综述了磁场对电化学腐蚀过程的影响.磁感应强度与腐蚀速率为非正相关关系,磁场在电极表面的不均匀分布与其腐蚀形貌有良好的对应关系.磁场对电化学过程的影响最主要体现在液相传质步骤,对由电子转移步骤控制的电化学过程的影响微乎其微,主要影响由液相传质控制的钝化、活化及其相互转变的过程,但洛仑兹力和磁场梯度力对电化学过程的作用不同.磁场对阴极极化的影响主要体现在对溶液中参与阴极去极化反应离子的作用.提出了磁场在与电化学有关方向潜在的应用前景和将来的发展方向.
参考文献
| [1] | Grant KM.;Hemmert JW.;White HS. .Magnetic field-controlled microfluidic transport[J].Journal of the American Chemical Society,2002(3):462-467. |
| [2] | Ragsdale S R;Grant K M;White H S .Electrochemically generated magnetic forces.Enhanced transport of a paramagnetic redox species in large,nonuniform magnetic fields[J].Joumalof the American Chemical Society,1998,120(51):13461-13468. |
| [3] | G. Hinds;J. M. D. Coey;M. E. G. Lyons .Influence of magnetic forces on electrochemical mass transport[J].Electrochemistry communications,2001(5):215-218. |
| [4] | Ghabashy M E;Sedahmed G H;Mansour I A S .Effect of a magnetic field on the rate of diffusion-controlled corrosion of metals[J].British Corrosion Journal,1982,17(01):36-37. |
| [5] | Chiba A;Kawazu K;Nakano O et al.The effects of magnetic fields on the corrosion of aluminum foil in sodium chloride solutions[J].Corrosion Science,1994,36(03):539-543. |
| [6] | Ghabashy M A .Effect of magnetic field on the rate of steel corrosion in aqueous solutions[J].Anti-Corrosion Methods and Materials,1988,35(01):12-13. |
| [7] | 田光,魏爱军,霍富永,李翠丽,高海霞.磁场对金属腐蚀的实验研究[J].管道技术与设备,2010(01):50-52. |
| [8] | Zhanpeng Lu;Delun Huang;Wu Yang;John Congleton .Effects of an applied magnetic field on the dissolution and passivation of iron in sulphuric acid[J].Corrosion Science,2003(10):2233-2249. |
| [9] | R. Sueptitz;J. Koza;M. Uhlemann;A. Gebert;L. Schultz .Magnetic field effect on the anodic behaviour of a ferromagnetic electrode in acidic solutions[J].Electrochimica Acta,2009(8):2229-2233. |
| [10] | Lu Z P;Shoji T;Yang W .Anomalous surface morphology of iron generated after anodic dissolution under magnetic fields[J].Corrosion Science,2010,52(08):2680-2686. |
| [11] | Sueptitz R;Tschulik K;Uhlemann M et al.Effect of high gradient magnetic fields on the anodic behaviour and localized corrosion of iron in sulphuric acid solutions[J].Corrosion Science,2011,53(10):3222-3230. |
| [12] | O'Brien R N;Santhanam K S V .Electrochemical hydrodynamics in a magnetic field with laser interferometry[J].Electrochimica Acta,1987,32(12):1679-1691. |
| [13] | 王超,陈慎豪.磁场作用下铁/硫酸体系阳极过程全息显微研究[J].腐蚀科学与防护技术,1999(01):13-23. |
| [14] | Quraishi M S;Fahidy T Z .The effect of magnetic fields on natural convective mass transport at inclined circular disk electrodes[J].Electrochimica Acta,1980,25:591-599. |
| [15] | Fahidy T Z .Magnetoelectrolysis[J].Journal of Applied Electrochemistry,1983,13(05):553-563. |
| [16] | Fahidy T Z .Hydrodynamic models in magnetoelectrolysis[J].Electrochimica Acta,1973,18(08):607-614. |
| [17] | Chopart J P;Douglade J;Fricoteaux P et al.Electrodeposition and electrodissolution of copper with a magnetic field:dynamic and stationary investigations[J].Electrochimica Acta,1991,36(34):459-463. |
| [18] | Aaboubi O;Chopart J P;Douglade J et al.Magnetic field effects on mass transport[J].Journal of the Electrochemical Society,1990,137(06):1796-1804. |
| [19] | Waskaas M;Kharkats Y I .Effect of magnetic fields on convection in solutions containing paramagnetic ions[J].Journal of Electroanalytical Chemistry,2001,502(01):51-57. |
| [20] | 吕战鹏,黄德伦,杨武.磁场作用下铁在盐酸和氯化钠溶液中自腐蚀状态的变化[J].腐蚀与防护,2002(05):185-189. |
| [21] | Zhanpeng Lu;Wu Yang .In situ monitoring the effects of a magnetic field on the open-circuit corrosion states of iron in acidic and neutral solutions[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2008(2):510-522. |
| [22] | 吕战鹏,黄德伦,杨武,赵国珍.含重铬酸根硫酸溶液中磁场对铁自腐蚀状态及极化电阻的影响[J].中国腐蚀与防护学报,2000(04):230-236. |
| [23] | Ralph Sueptitz;K. Tschulik;M. Uhlemann;A. Gebert;L. Schultz .Impact of magnetic field gradients on the free corrosion of iron[J].Electrochimica Acta,2010(18):5200-5203. |
| [24] | Fernando M. F. Rhen;G. Hinds;J. M. D. Coey .Magnetic field effect on the rest potential of zinc[J].Electrochemistry communications,2004(4):413-416. |
| [25] | Lu Z P;Huang D L;Yang W .Probing into the effects of a magnetic field on the electrode processes of iron in sulphuric acid solutions with dichromate based on the fundamental electrochemistry kinetics[J].Corrosion Science,2005,47(06):1471-1492. |
| [26] | Sueptitz R;Tschulik K;Uhlemann M et al.Magnetic field effects on the active dissolution of iron[J].Electrochimica Acta,2011,56(17):5866-5871. |
| [27] | 王晨;陈俊明.磁场对铁腐蚀过程中阴极析氢和阳极溶解的影响[J].中国腐蚀与防护学报,1994(02):123-128. |
| [28] | Zhanpeng Lu;Chunbo Huang;Delun Huang;Wu Yang .Effects of a magnetic field on the anodic dissolution, passivation and transpassivation behaviour of iron in weakly alkaline solutions with or without halides[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2006(10):3049-3077. |
| [29] | Li, L;Wang, WJ;Wang, C;Chen, SH .Effects of an applied magnetic field on the anodic dissolution of nickel in HNO3 + Cl- solution[J].Electrochemistry communications,2009(11):2109-2112. |
| [30] | Wang X P;Zhao J;Hu Y et al.Effects of the Lorentz force and the gradient magnetic force on the anodic dissolution of nickel in HNO3 + NaCl solution[J].Electrochimica Acta,2014,117:113-119. |
| [31] | 曹楚南.腐蚀电化学原理[M].北京:科学技术出版社,1987:74-75. |
| [32] | Z. Diao;P.A. Dunne;G. Zangari;J.M.D. Coey .Electrochemical noise analysis of the effects of a magnetic field on cathodic hydrogen evolution[J].Electrochemistry communications,2009(4):740-743. |
| [33] | 吕战鹏,杨武,黄德伦,赵国珍.磁场对铜在含三价铁离子硫酸溶液中的腐蚀行为的影响[J].中国腐蚀与防护学报,2001(03):129-136. |
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