制备了Nd3+∶ZnO-B2O3-Al2O3-SiO2系透明玻璃陶瓷.运用差热分析(DTA)、X射线衍射(XRD)、扫描电镜(SEM)、NV-Vis-Nir(紫外可见近红外分光光度计)、傅里叶变换荧光光谱等测试方法,研究了晶核剂的含量对Nd3∶ZnO-B2O3-Al2O3-SiO2系透明玻璃陶瓷的核化和晶化性能的影响.利用修正的Kissinger方程研究了晶核剂对玻璃析晶动力学参数,析晶活化能E和析晶动力学判据k(Tp),利用Augis-Bennett方程计算出Avrami参数n.并分析其显微形貌同光透过率的关系,对光学性能进行了研究.
参考文献
| [1] | McMil1an.Glass-ceramics[M].London,UK:Academic Press,1979 |
| [2] | 程金树.微晶玻璃[M].北京:化学工业出版社,2006 |
| [3] | Martin Locher;Valerio Romano;Heinz P. Weber .Rare-earth doped sol-gel materials for optical waveguides[J].Optics and Lasers in Engineering,2005(3/5):341-347. |
| [4] | M. Mortier;A. Bensalah;G. Dantelle;G. Patriarche;D. Vivien .Rare-earth doped oxyfluoride glass-ceramics and fluoride ceramics: Synthesis and optical properties[J].Optical materials,2007(10):1263-1270. |
| [5] | Wang Y;Ohwaki J .New Transparent Vitroceram ics Codoped with Er3 + and Yb3 + for Efficient Frequency Upconvers ion[J].Applied Physics Letters,1993,63:3268-3270. |
| [6] | Vincent Seznec;Hong Li Ma;Xiang Hua Zhang;Virginie Nazabal;Jean-Luc Adam;X.S. Qiao;X.P. Fan .Preparation and luminescence of new Nd~(3+) doped chloro-sulphide glass-ceramics[J].Optical materials,2006(4):371-376. |
| [7] | R.K. Verma;D.K. Rai;S.B. Rai .Investigation of structural properties and its effect on optical properties: Yb~(3+)/Tb~(3+) codoped in aluminum silicate glass[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2011(18):5591-5595. |
| [8] | P.A.Tick;N.F.Borrelli;I.M.Reaney .The relationship between structure and transparency in glass-ceramic materials[J].Optical materials,2000(1):81-91. |
| [9] | Alekseeva, I.;Dymshits, O.;Tsenter, M.;Zhilin, A.;Golubkov, V.;Denisov, I.;Skoptsov, N.;Malyarevich, A.;Yumashev, K. .Optical applications of glass-ceramics[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2011(52/54):3042-3058. |
| [10] | Dejneka MJ. .The luminescence and structure of novel transparent oxyfluoride glass-ceramics[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1/3):149-155. |
| [11] | 张洪波,苏春辉,王轶敏,邵晶,许素莲,朱晓薇,张华山.掺钕氟氧化物玻璃陶瓷的制备及表征[J].高等学校化学学报,2008(04):677-680. |
| [12] | 李茜琪,陈新政,范仕刚.Yb： YAG微晶玻璃的制备与性能研究[J].人工晶体学报,2010(01):163-168,173. |
| [13] | 顾牡,孙心瑗,黄世明,金鑫杰,刘波,刘小林,倪晨.透明SiO2-Al2O3-CaO-CaF2 微晶玻璃中Tb3+的发光性能研究[J].人工晶体学报,2009(02):321-325. |
| [14] | 许杰,高峰.锌硼硅-氧化铝微晶玻璃的制备及性能[J].硅酸盐学报,2009(03):409-413. |
| [15] | 徐洋,钟朝位,周晓华,张树人.低温共烧氧化铝/玻璃复合基板材料的研究[J].材料开发与应用,2007(06):20-23,44. |
| [16] | 吴茂,曲选辉,何新波,罗大为,敖洪.ZnO-Al_2O_3-B_2O_3-SiO_2系微晶玻璃与可伐合金的润湿性能[J].材料热处理学报,2009(06):25-30. |
| [17] | 杨秋红;姜中宏 .玻璃析晶动力学判据研究[J].硅酸盐学报,1994,22(10):419-426. |
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