在100 g钴矿加入39 mL浓硫酸、浸出温度80 ℃、浸出时间2 h、液固比2-1时,采用常规的硫酸浸出,钴浸出率仅为16.86%;当100 g钴矿中加入42.5 mL浓硫酸、在焙烧温度630 ℃、焙烧时间1.5 h的焙烧条件下,采用硫酸化焙烧后硫酸浸出,钴浸出率达到67.48%;在100 g钴矿中加入39 mL浓硫酸和56 mL浓硝酸、浸出温度60 ℃、浸出时间4 h、液固比为3-1时,采用硝酸氧化下硫酸浸出,钴浸出率为96.35%.
参考文献
[1] | R.H. Matjie;M.M. Mdleleni;M.S. Scurrell .Extraction of cobalt(II) from an ammonium nitrate-containing leach liquor by an ammonium salt of di(2-ethylhexyl)phosphoric acid[J].Minerals Engineering,2003(10):1013-1017. |
[2] | M.V. Rane;V.H. Bafna;R. Sadanandam .Recovery of high purity cobalt from spent ammonia cracker catalyst[J].Hydrometallurgy,2005(3/4):247-251. |
[3] | Basudev Swain;Jinki Jeong;Jae-chun Lee .Development of process flow sheet for recovery of high pure cobalt from sulfate leach liquor of LIB industry waste: A mathematical model correlation to predict optimum operational conditions[J].Separation and Purification Technology,2008(2):360-369. |
[4] | C.Kargl-Simard;J.H. Huang;A.M. Alfantazi .Electrical conductivity and density of CoSo_4/H_2SO_4 solutions in the range of modern cobalt electrowinning electrolytes[J].Minerals Engineering,2003(6):529-535. |
[5] | J. Jandova;H. Vu;P. Dvorak .Treatment of sulphate leach liquors to recover cobalt from waste dusts generated by the glass industry[J].Hydrometallurgy,2005(1/2):67-73. |
[6] | I. G. Sharma;P. Alex;A. C. Bidaye .Electrowinning of cobalt from sulphate solutions[J].Hydrometallurgy,2005(1/2):132-138. |
[7] | 张义忠;谢刚;李荣兴;杨棣 .从铜钴尾矿中提钴的浸出实验研究[J].中国稀土学报,2008,26:132-137. |
[8] | 丰成友,张德全,党兴彦.中国钴资源及其开发利用概况[J].矿床地质,2004(01):93-100. |
[9] | R. Sadanandam;M.F. Fonseca;K. Srikant .Production of high purity cobalt oxalate from spent ammonia cracker catalyst[J].Hydrometallurgy,2008(1/4):28-34. |
[10] | 侯慧芬.从各种含钴原料中提取电解钴[J].上海有色金属,2001(03):132-137. |
[11] | 曹异生.钴工业现状及发展前景[J].中国金属通报,2006(01):6-9. |
[12] | 兰玮锋,米玺学.从氧化钴矿石中提取钴的试验研究[J].湿法冶金,2008(04):230-233. |
[13] | 谢福标.含钴废料回收工艺述评[J].矿冶,2003(01):63-66,59. |
[14] | 李安国,廖春发,饶先发.从含钴废料中回收钴的研究进展[J].中国资源综合利用,2009(02):16-18. |
[15] | 杨遇春.再生钴的生产现状和开发前景[J].中国资源综合利用,2001(09):16-22. |
[16] | 刘三平,王海北,蒋开喜,王玉芳.钴提取分离技术分析与应用[J].有色金属,2004(02):73-76. |
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