研究了高铌TiAl合金Ti-44Al-8Nb-0.2W-0.1B-0.1Y (at%)分别与Al2O3/ZrO2/Y2O3坩埚的界面反应.测得界面反应层的厚度分别为40,170和20 μm.研究中最大的发现在于Ti-44Al-8Nb-0.2W-0.1B-0.1Y(at%)合金在3种坩埚中凝固后显微组织的转变.经测定该合金在3种坩埚中凝固获得的试样中氧含量分别为0.35,0.41和0.11 (at%).由于在合金熔化和凝固过程中,坩埚中的氧元素扩散进入合金基体,较高的氧含量导致合金显微组织发生转变,在与Al2O3和ZrO2坩埚反应的合金中发生了包晶反应.作为对比,选取一种低铌含量的TiAl合金Ti-49.5Al-2Cr-2Nb.经测定在3种坩埚中反应的氧含量分别为0.40,0.63和0.25 (at%),但是组织却没有明显的差异.
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