采用动电位极化和电化学阻抗法研究了X80和X70管线钢在0.5 mol/L NaHCO3+0.02 mol/L NaCl溶液中的腐蚀行为,并通过电容测量方法对其腐蚀机理进行了探讨.结果表明:在0.5 mol/L NaHCO3+0.02 mol/L NaCl溶液中,X80管线钢的点腐蚀电位Epit比X70钢的要正一些,发生点腐蚀的倾向性更小.Mott-Sehottky分析表明:X80比X70管线钢表面钝化膜内的施主密度更低,缺陷数量更少,从而减少了点腐蚀萌生的潜在位置,使X80钢比X70钢具有更好的耐点蚀性能.
参考文献
[1] | 冯耀荣,庄传晶.X80级管线钢管工程应用的几个问题[J].焊管,2006(01):6-10. |
[2] | 黄志潜.X80级管线钢在高压大流量输气管道上的应用与发展前景[J].焊管,2005(02):1-10. |
[3] | 罗金恒,王曰燕,赵新伟,王荣,郑茂盛.在役油气管道土壤腐蚀研究现状[J].石油工程建设,2004(06):1-6. |
[4] | J.-J. Park;S.-I. Pyun;K.-H. Na .Effect of Passivity of the Oxide Film on Low-pH Stress Corrosion Cracking of API 5L X-65 Pipeline Steel in Bicarbonate Solution[J].Corrosion: The Journal of Science and Engineering,2002(4):329-336. |
[5] | J.G. Gonzalez-Rodriguez;M. Casales;V.M. Salinas-Bravo .Effect of Microstructure on the Stress Corrosion Cracking of X-80 Pipeline Steel in Diluted Sodium Bicarbonate Solutions[J].Corrosion: The Journal of Science and Engineering,2002(7):584-590. |
[6] | 杨武.埋地油气管线应力腐蚀破裂研究的一些新进展[J].腐蚀与防护,2003(11):461-467. |
[7] | Chen YY;Chou LB;Shih HC .Effect of solution pH on the electrochemical polarization and stress corrosion cracking of Alloy 690 in 5 M NaCl at room temperature[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2005(1/2):129-137. |
[8] | 林玉华,杜荣归,胡融刚,林昌健.不锈钢钝化膜耐蚀性与半导体特性的关联研究[J].物理化学学报,2005(07):740-745. |
[9] | Y. F. Cheng;J. L. Luo .Electronic structure and pitting susceptibility of passive film on carbon steel[J].Electrochimica Acta,1999(17):2947-2957. |
[10] | Pagitsas M;Diamantopoulou A;Sazou D .A point defect model for the general and pitting corrosion on iron vertical bar oxide vertical bar electrolyte interface deduced from current oscillations[J].Chaos, Solitons and Fractals: Applications in Science and Engineering: An Interdisciplinary Journal of Nonlinear Science,2003(2/3):263-275. |
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