采用水热法经过煅烧热处理成功制备了ZnWO4∶Sm3+白色荧光粉.通过X射线粉末衍射仪,扫描电子显微镜及荧光分光光度计对样品的物相结构、形貌粒度及发光性能进行了分析和表征.结果表明:在pH值为6和7下,所合成的ZnWO4∶Sm3+晶体结构与ZnWO4相似,为单斜晶系结构,样品颗粒为类球形,颗粒尺寸范围为100 ～ 220 nm.Sm3的摩尔掺杂量为0.5％时,发射峰强度达到最大值;继续增加Sm3+浓度,其发射峰强度反而减弱,出现了浓度猝灭效应.在254 nm波长激发下,ZnWO4∶Sm3+的色坐标集中在冷白光区.
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